Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The plant consists of simple subliming furnaces, iron cooling pipes,
suction fans, and a series of flannel or calico bags, arranged
vertically in a building, well ventilated, so as to allow the filtered
gases to escape, leaving behind the sublimed white lead, which is then
merely shaken down from the bags into barrels placed beneath them. The
manufacture is carried on at Joplin, Missouri, with four subliming
furnaces, about 500 feet of cooling pipes and towers, with suction
fans, which drive the fumes into 300 bags, 20 inches in diameter,
and 38 feet long, arranged vertically. About 50 tons weekly of white
lead are now being produced from waste fumes, slag, and poor ore, by
this establishment alone, at a cost not exceeding that given in the
following figures:--
£ _s._ _d._
20 cwt. of galena (with 82 per cent, of ore) 8 0 0
Cost of subliming and catching, including repairs,
labour and all expenses 1 10 0
Casks 0 6 0
------------
9 16 0
Freeman’s process (see p. 254) consists of grinding together, in a dry
state, under great pressure, and consequently with great friction,
sulphate of lead and sulphate of zinc. While neither of these two
substances alone possesses good body or opacity, when treated by this
process they are so changed in character that the new substance is
stated to be superior in these respects to the best form of ordinary
white lead.
The white lead thus obtained mixes well with oil, and has also the
advantage of not becoming blackened when exposed to the fumes of
sulphuretted hydrogen, and of not peeling off in a saline atmosphere.
As a basis for coloured paints, it is recommended on the ground that,
being decomposed with greater difficulty, it can be mixed with almost
any colouring substance; and, being free from acid, it does not change
the tints of other substances.
The details of Lewis’s process, and the plant employed, are more fully
set forth below.
Heretofore the manufacture of dry white lead from galena or the
native sulphurets has been effected by roasting or desulphurising the
galena, and then mixing the residue, after roasting, with carbon, and
subjecting the mixture to the action of heat in a compound reducing or
subliming and oxidising furnace, and collecting the resulting fumes in
textile bags.
Public-domain text, read in full here on John Shaqi.
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