Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
It is believed that the production of white lead in Italy during the
first ten years of this century was about 300 tons per annum. The total
annual production at present is, in round numbers, about 3500 tons, of
which 2800 are produced in the Ligurian manufactories, and about 300 in
those of Naples. Milan also produces about 300 tons.
The product finds a market almost exclusively in Italy. The annual
amount exported is about 300 tons, and goes chiefly to Constantinople.
Of the quantity of 2000 tons per annum produced at Cogoleto, about 300
tons is sold mixed with oil. No exact statistics are attainable as to
the total amount of Italian white lead which is annually sold other
than in the dry state, but it is believed to be little, if any, larger
than 300 tons.
When the price of white lead was high, sulphate of baryta was mixed
with carbonate of lead to produce white lead of inferior quality, but
in consequence of the present price of white lead the use of sulphate
of baryta has almost entirely ceased. No other methods of adulteration
are known to be in use. In Italy, white lead is universally known as
“_biacca_” when it is sold in cakes. When sold in powder it is known as
“_carbonato di piombo_” (carbonate of lead). The lead from which all
the white lead made in Italy is manufactured comes from the lead mines
of the island of Sardinia, with the exception of a very small quantity
of argentiferous lead coming from Spain. The acetic acid used in the
process of manufacture comes from France. The market price of white
lead in Italy is now about 45 lire the quintal (equivalent to 18_s_.
per cwt.).
_Lewis’s Process._--Many attempts have been made to substitute for
carbonate of lead--the ordinary poisonous white lead, that slowly but
surely induces paralysis in those who come in contact with it for any
considerable period--some less deleterious pigment. Zinc white has
often been put forward as a substitute, and is indeed largely employed;
but it is open to the objection of not possessing sufficient body or
opacity. Sulphate of lead is not poisonous; but, when prepared in
the ordinary way by precipitation, is of a crystalline nature, and,
therefore, wanting in both these qualities.
A sulphate of lead has, however, been produced by John T. Lewis, of
Philadelphia, by sublimation, which, when treated by the Freeman
process, is stated to possess a body and colour superior to the best
white lead made by the ordinary process, with the additional merit of
being cheaper, while it is also non-poisonous.
In the smelting of lead ore into pig lead, 15 per cent. goes off
in fumes, and 10 per cent. are all that it has hitherto been found
possible to recover; by this process, however, the whole 15 per cent.
are recovered. The sulphate may also be produced from a low quality of
galena, or lead ore, which is not suited for smelting into metallic
lead, and from the slag formed in the process of smelting.
Public-domain text, read in full here on John Shaqi.
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