Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The temperature of the liquor may vary between 140° F. and 212° F.;
but within these limits, the lowest temperature consistent with
the sufficiently rapid conversion and solution of the litharge is
preferable. The reason of this is simply that the less the heat
employed, the less is the tension of the ammonia, and the chances of
the loss of ammonia are thus minimised; in addition to this, less
delay is involved and less refrigeration or cooling is needed before
carbonating.
The object of the violent agitation of the litharge amongst the heated
acetate of ammonium in the digestor _a_, is that caking of the former
may be prevented, and a most rapid conversion of the oxide of lead into
basic acetate of lead, with minimum expenditure of heat, be secured.
The effect of the heat in the closed space is greatly aided by that of
the pressure due to the tension of the ammonia and aqueous vapour at
the increasing temperatures.
When the litharge is converted into tribasic acetate of lead, and
brought into solution, the liquor and sludge of insoluble matters is
preferably pumped through pipe _k_, by means of the filter-press pump
_l_, and forced through the filter-press _m_, which removes and retains
the insoluble matter, allowing the clear liquor to pass to the cooler
_n_, and through this to the carbonator _o_, similar in construction to
the digestor _a_.
Here the cooled liquid is circulated by means of pump _p_ (in a similar
manner to that adopted in the digestor process already described),
carbonic acid being simultaneously pumped in through the pipe _q_,
which is perforated as shown, or introduced in any other way.
When carbonated to the desired extent, the white magma, consisting of
basic carbonate of lead and mother liquor, is drawn through the pipe
_r_, by the pump _s_, into the filter press _t_.
The clear liquid flows through _u_, into the covered mother liquor tank
_v_, whilst the press-cakes of white lead, after sufficient washing
with water, are removed and dried in a suitable manner.
The washings are run off to a weak liquor tank (not shown) for
concentration for use over again. Any inert gases accompanying the
carbonic acid, or the latter alone in excess, pass from the carbonator
through pipe _w_, into the catch-box or other condensing and absorbing
apparatus _x_, containing either dilute acetic acid or cold water, in
order to retain any ammonia carried over, and furnished with perforated
trays or baffle-plates.
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