Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
This catch-box is, if necessary, also connected with a further
condenser, so as to remove all ammonia from the displaced air, or
inert gases (if impure carbonic acid has been used) of the carbonator.
It is a lead lined vessel preferably. The ammonia carried from each
charge thus is tested by measuring the volume of the solution from the
catch-box or other condensing and absorbing apparatus, and estimating
the ammonia present in the solution. This amount of ammonia in a
sufficiently concentrated form is then added to the charge in the
carbonator, when cold, so as to produce a completely neutral solution.
The ammonia in the catch-box is either added to the ammonia stock
in the ammonia department, used for dilution of strong ammonia in
making fresh acetate, or strengthened up to further absorption in the
catch-box or condenser, until strong enough to add to a freshly run and
cooled charge in the carbonator, to replace any ammonia driven off by
heat.
The sludge in the filter-press _m_ is washed with water to remove
acetate liquors and ammonia, the weak liquors being run to a separate
closed vessel similar to the carbonator _o_, but smaller, and not shown
in the drawing.
Here white lead is precipitated by carbonic acid, and the product is
passed into the filter-press _t_, the weak liquors associated with it
serving to give a preliminary washing to a freshly received charge
of white lead already in the press. The weak filtrate liquors thus
obtained are preferably sent to the weak liquor tank already mentioned,
for subsequent concentration, instead of to the stronger liquor tank
_v_.
The sludge-cakes from the filter-press _m_, connected with the
digestor, are suitably treated for the recovery of lead therefrom.
The mother liquors contained in tank _v_ from the white lead
filter-press _t_, are directly returned to the ammonium acetate tank
_y_, by the pump _z_, for use over again.
The carbonators may be operated singly as described, or two or three
may be connected together so as to be worked in rotation, the partially
absorbed carbonic acid from one carbonator being completely, or more
or less completely, absorbed in the one, or two, with which it is
connected. The last of such series of carbonators would of course be
connected with the catch-box arrangement previously described, or other
condensing and absorbing apparatus.
_Characters._--The advantages and disadvantages in the employment of
white lead have been described pretty fully by Prof. Barff in one of
the Cantor series of lectures which form such an important feature in
the publications of the Society of Arts.
Public-domain text, read in full here on John Shaqi.
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