Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Chromates of lead, says Prof. Barff, are produced by precipitating a
lead salt with a salt of chromic acid, and the difference in tint is
owing to the different quantity of the chromic acid which is present
in the salt. The orange chrome is a basic chromate of lead, and basic
chromate of lead contains more of the chromic acid than is present in
the lemon chrome. The lightest chrome contains some sulphate of lead
precipitated with the chromate. All these colours contain lead, and
are therefore liable to the influence of sulphuretted hydrogen. Now,
if a chromate of lead is bought hap-hazard anywhere, it may or may not
be pure, but generally speaking, unless the chromates are obtained
from makers who are careful in the preparation of their colours, they
contain many other substances besides chromate of lead. For instance,
they contain a quantity of the solution, in a dry state, from which
they have been precipitated, and are by no means pure. Obviously, also,
there is an inducement to men who sell cheap colours to adulterate
them, to bring them down with whiting, and so forth. In that case the
chrome loses its body; if it is brought down with lead sulphate it has
more body; but when chrome yellows are prepared and mixed with good
oils, and put on carefully, and those oils have time allowed them to
become oxidised, perfectly dry in fact--not dry in the sense in which
an artist considers a painting dry, but perfectly hard--then the action
of sulphuretted hydrogen in the atmosphere will not be of such great
moment as if the colours are impure, or if they are submitted to the
influence of that deleterious gas before they have become perfectly
hard.
Another objection to the chromes, on the authority of Prof. Barff, is
that they are soluble in alkali, and so are many other colours. If
a painting is painted with chromes, and if that painting be washed
with an alkaline soap, it is quite certain that some of the chromates
will be dissolved. Consequently the minute and delicate touches, upon
which the artist depended for some of the best effects of his picture,
are removed with soap and water. No painting should ever be washed
with soap and water at all; but there are certain colours which will
withstand the action of soap, even if it is intensely alkaline, while
others will not. Taking a precipitate of lemon chrome, if we act upon
this with potash or soda, it dissolves up the yellow precipitate, and
destroys it altogether.
Public-domain text, read in full here on John Shaqi.
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