Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
AUREOLIN YELLOW.--This colour is prepared by precipitating
carbonate of cobalt from a solution of a cobalt salt with carbonate
of potash; this precipitate is dissolved in acetic acid, and to it is
added nitrite of sodium; nitrite of potassium and cobalt are thrown
down as a yellow powder. Experiments made on the freshly-precipitated
colour prepared in this way, have proved it to be invariably destroyed
by caustic potash; but aureolin yellow prepared in another way, put
into a flask with some caustic soda, has remained unchanged for several
days, and proved to be perfectly stable under this treatment. Samples
of the same yellow, exposed to the action of ammonia, soda, and potash
for a considerable length of time, have not changed. This is really a
most important fact, because aureolin yellow is so beautiful a pigment
that one wishes it would stand for ever. It is, in fresco and silicious
painting, a great desideratum to have colours that will stand the
action of lime and caustic alkalies. Our colours for fresco painting
are very limited, and if aureolin will stand the action of caustic
alkalies, it may be safely used both for fresco and silicious painting.
CADMIUM YELLOW.--The pigment known as cadmium yellow is
important on account of its permanence and brilliance. It is prepared
by passing a stream of sulphuretted hydrogen gas through a slightly
acid solution of a salt of cobalt, usually the nitrate or sulphate,
whereby the sulphide of cadmium is precipitated as an impalpable
powder. It is filtered off, well washed with water, and finally dried
at a low temperature.
By this method there is considerable difficulty in producing any
precise, shade of yellow, which is dependent on the proportion of
precipitant used, and can only be controlled after long practical
experience. Therefore some modifications have been introduced with
the object of securing definite tints. The ordinary colour is a pure
chrome yellow. For a lemon-yellow shade, a solution of yellow sulphide
of ammonium is added to one of sulphate of cadmium. For an orange
tint, the cadmium solution (chloride or sulphate) is made very acid by
addition of hydrochloric acid before passing the sulphuretted hydrogen;
or the cadmium solution, as for lemon-yellow, is boiled, and receives
the ammonium sulphide solution while still boiling. But none of these
modifications results in a really durable pigment, on account of the
presence of traces of free sulphur or acid.
The best brands of this pigment being somewhat expensive, there is
great inducement for adulteration, which usually takes the form of
orpiment or of chrome. The former can be detected by the ordinary tests
for arsenic, and the latter by the process described on p. 266.
CHROME YELLOWS.--A very important family of yellow pigments
are the “chromes,” consisting mainly of chromic acid in combination
with lead, iron, or zinc.
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