Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
After the galena is dissolved by the nitric acid, and the sulphide of
lead is changed into liquid plumbic nitrate, then the sulphur which
floats occasionally on the surface of the solution is removed, and the
substance which remains undissolved is washed out and is also removed.
The liquid nitrate is then passed through filters of felt, linen, hemp,
flannel, &c., or is left standing for about 12 to 18 hours for settling
and clearing.
Now in order to produce the chrome yellow from this nitrate of lead,
bichromate of potash is dissolved in water, and a sufficient quantity
of this solution is poured into the plumbic nitrate solution until all
the plumbic nitrate is changed into chromate of lead, called “chrome
yellow.” Instead of the bichromate of potash, neutral chromate, or
chromate of soda may be used, and for the purpose of obtaining lighter
tints they may be tempered with sulphuric acid or any other compound
of sulphur. The liquid nitrate of lead is placed, preferably, in
large open receptacles of wood, clay, earthenware, or other suitable
material, and the chromate of potash solution is put into similar
vessels, and then placed above the receptacles containing the plumbic
nitrate. The chromate of potash can then easily be run into the lower
receptacles containing the liquid nitrate of lead, and this mixture is
constantly agitated by similar means until all the plumbic nitrate is
changed into chromate of lead, which is precipitated on the bottom of
the larger receptacles.
The chemical action which takes place by this changing of nitrate of
lead into chromate of lead is that the chromic acid of the potash
assumes the place of the nitric acid, which parts from the lead and
combines with the potassium, so that the lead as chromate of lead is
precipitated on the bottom of the receptacle, while the nitric acid of
the plumbic nitrate remains with the potassium, which latter has parted
with its chromic acid, and a quantity of water as solution above the
chromate of lead.
To change the nitrate of lead recovered out of the 100 lb. of galena
above mentioned into chromate of lead, about 56 lb. of bichromate of
potash are used. This change usually takes place in from about 10 to
30 minutes, after which the chrome yellow (chromate of lead) is left
for a few hours to settle, and then the solution standing on top of the
chrome yellow is drawn off by suitable means, or run out of the vessel
by opening a cock placed above the level of the chromate of lead.
The latter is then washed by adding pure water, which is poured
upon the chrome yellow, and the mixture is stirred up, so that all
the remaining liquid nitrate of potash is removed. After this is
accomplished, the mass is left to settle, and the water is again drawn
off from the precipitate, which then settles on the bottom of the
receptacle. This washing is repeated as often as is deemed necessary.
Public-domain text, read in full here on John Shaqi.
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