Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The chrome yellow is next placed in suitable receptacles, and dried in
the open air or in specially constructed drying rooms, after which it
is packed in boxes, kegs, &c., and is then ready for use. The liquid
nitrate of potassium, or saltpetre lye, removed from the receptacles
in which the chrome yellow is precipitated, and the first water used
for washing the chrome yellow, as above described, are placed in
large open flat receptacles or excavations, so as to be exposed to
the action of the air and sun; or the liquids may be operated on by a
small graduation work, so that a great portion of water evaporates. The
residue is then heated in suitable vessels or troughs by a slow heat
until a salt crust is formed, which, when cooled off and left to dry,
is nitrate of potassium or saltpetre in a pure state.
From 100 lb. of galena having 80 per cent. metallic lead, some 28 to
30 lb. of pure and dry saltpetre are produced by the above described
process. The sulphur produced by the dissolving of the galena by nitric
acid is melted in a small stove or furnace in the usual manner, and
then refined, so as to produce bars of sulphur called “brimstone.”
About 10 lb. of such sulphur are produced from 100 lb. of such galena
treated in the manner described.
The chrome yellow thus produced is said to be chemically pure, and of
great covering power, equal to the best chrome yellow in the market.
The process is very simple, and the crude lead ore is transformed into
chrome yellow in from three to four days.
_Characters._--Pure chromate of lead has an orange-yellow colour, and
in whatever manner it be made it always has this tint. Commercially,
chromes are made of a great variety of tints, from a pale-lemon chrome
to a deep scarlet, through all the intermediate shades of yellows and
oranges; in fact, most colour makers produce not less than eight, and
some more shades of chromes, whence it is obvious that they cannot be
chemically pure, but must be mixed with some other bodies.
In commerce, chromes are distinguished as “pure” and “common”: the
distinction between them is that the “pure” chromes are made from a
lead base, and consist of chromate of lead mixed to a larger or smaller
amount with sulphate of lead, the paler shades containing most of the
latter; while the “common” chromes are mixed with china clay, barytes,
gypsum, or similar bodies.
To distinguish the two kinds of chromes, treat with boiling
hydrochloric acid. If pure, the chrome will completely dissolve, the
solution usually having a green colour. On cooling, crystals of lead
chloride separate out. The liquor will give a white precipitate with
barium chloride.
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