Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
By taking a weighed quantity of chrome, dissolving in hydrochloric
acid, adding excess of barium chloride, filtering, thoroughly washing
the precipitate with _boiling_ water, drying and weighing it, and
making the necessary calculations, every one part of the precipitate
being equal to 1·3 parts of sulphate of lead, the quantity of the
latter in the chrome is obtained.
The “common” chromes, which mostly contain barytes, are not completely
dissolved on boiling in hydrochloric acid, the barytes they hold being
left as an insoluble residue. By taking a weighed quantity of the
chrome, and filtering off, drying and weighing the residue, the amount
of barytes present can be ascertained; the solution can be tested for
sulphate of lead, which they sometimes contain, as described above.
Chrome yellows and oranges should be assayed for colour and tint,
care being taken to compare them with a thoroughly reliable standard
sample. Their colouring power and body should also be assayed. Another
property which should be tested is the colour that they yield on mixing
with Prussian blue. A great deal of chrome is used for making greens
by mixing with Prussian blue, and as there is a very considerable
difference between them in the shade of green they give, it is rather
important to test this property, which can readily be done by mixing
100 grains of the chrome with 10 grains of Prussian blue, grinding them
together in a mortar, and observing the shade of the green which is
produced thereby; if the green is not bright and pure, the chrome is
not fit to be made into greens, and should be rejected for that purpose.
_Iron Chromate._--If a solution of chloride of iron acidulated with
hydrochloric acid be added to neutral chromate of lead, a light orange
powder is precipitated, which is chromate of iron. Dried at 104° F.,
it is found to consist of 65 to 65·11 chromic acid, and 34·58 to 34·78
oxide of iron. Chromate of iron is insoluble in water, dissolves easily
in hydrochloric, nitric, and sulphuric acids, and decomposes when
mixed with soda lye. Under strong heat, it melts into a brownish mass.
It may be used in painting in oils, as a substitute for chromate of
lead. Although inferior to the latter in brilliancy, it has certain
advantages over it--it does not blacken with exposure to sulphuretted
hydrogen, is not injurious to the user, and withal is cheaper.
Public-domain text, read in full here on John Shaqi.
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