Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The luminous calcic sulphide (also called sulphide of calcium),
now obtainable in the market, has a yellowish white tint, which
considerably limits its direct application as a paint. On the other
hand, the calcic sulphide, or the luminous paint obtained therefrom,
loses its luminous property, if it is directly mixed with the ordinary
commercial paints.
Schatte, of Dresden, produces durable white or coloured paints,
containing a luminous substance which causes them to shine in the dark,
without changing or neutralising in daylight the tint of the colouring
substance or substances contained in such paints.
For this purpose, Zanzibar or cowrie copal is melted over a charcoal
fire, 15 parts of this melted mass are dissolved in 60 parts of French
turpentine, and the resulting mixture is filtered, whereupon 25 parts
of pure linseed oil are added, which linseed oil has been previously
boiled and allowed to cool a little. The lake varnish thus obtained is
carefully treated in a paint mill with granite rollers, and worked into
a luminous paint by one of the processes hereinafter described.
Iron rollers capable of giving off under great pressure small particles
of iron, which might affect the luminous power, should not be used.
Lake varnish as obtained in commerce contains nearly always lead
or manganese, which would destroy the luminous power of the calcic
sulphide.
The proportions given are as follows:--
_Pure White_: By mixing 40 parts of lake varnish obtained as described
with 6 parts of prepared baric sulphate, 6 parts of prepared calcic
carbonate, 12 parts of prepared zinc sulphide white, and 36 parts of
calcic sulphide in a luminous condition, in an oil vessel, and worked
into a coarse emulsion, which is then ground fine between the rollers.
_Red_: 50 parts of the said lake varnish are mixed with 8 parts of
prepared baric sulphate, 2 parts of prepared madder lake, 6 parts of
prepared realgar (diarsenious disulphide), and 34 parts of calcic
sulphide in a luminous condition, and the mixture is worked in the same
way as described for white.
_Orange_: 46 parts varnish are mixed with 17·5 parts prepared barium
sulphate, 1 part prepared India yellow, 1·5 parts prepared madder lake,
and 38 parts luminous calcium sulphide.
_Yellow_: 48 parts varnish are mixed with 10 parts prepared barium
sulphate, 8 parts barium chromate, and 34 parts luminous calcium
sulphide.
_Green_: 48 parts varnish are mixed with 10 parts prepared barium
sulphate, 8 parts chromium oxide green, and 34 parts luminous calcium
sulphide.
_Blue_: 42 parts varnish, 10·2 parts prepared barium sulphate, 6·4
parts ultramarine blue, 5·4 parts cobalt blue, and 46 parts luminous
calcium sulphide.
_Violet_: 42 parts varnish, 10·2 parts prepared barium sulphate,
2·8 parts ultramarine violet, 9 parts cobalt arsenate, and 36 parts
luminous calcium sulphide.
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