Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Linseed-oil, to be suitable for painting, must dry well. A reliable
test is to cover a piece of glass with a film of the raw oil, and to
expose it to a temperature of about 100° F. The time which the film
requires to solidify is a measure of the quality of the oil. If the
oil has been extracted from unripe or impure seed, the surface of the
test-glass will remain “tacky” or sticky for some time, and the same
will happen if the oil under examination has been adulterated with
either an animal or vegetable non-drying oil.
Until recently, linseed oil was frequently adulterated with cotton-seed
oil, extracted from the waste seeds of the cotton plant. Where the
admixture was considerable, it could easily be detected by the sharp,
acrid taste of the cotton-seed oil. Now, however, means have been found
for removing this disagreeable taste, and the consequence has been that
cotton-seed oil is so largely used for adulterating olive-oil, or as a
substitute for it, that its price has risen above that of linseed oil.
Another adulterant which is rather difficult to detect is rosin. Oil
containing this substance is thick, and darker in colour than pure
oil. When the proportion of rosin is considerable, its presence may be
ascertained by heating a film of the oil upon a metallic plate, when
the characteristic smell of burning rosin will be perceptible. When the
percentage of rosin is too small for detection in this manner, a film
of the oil should be spread upon glass and allowed to dry. When quite
hard, the film should be scraped off, and treated with cold turpentine,
which will dissolve any rosin which may be present, without materially
affecting the oxidised oil. The presence of rosin may also be detected
by the following simple chemical test. The oil is boiled for a few
minutes with a small quantity of alcohol (sp. gr. O·9), and is allowed
to stand until the alcohol becomes clear. The supernatant liquid is
then poured off, and treated with an alcoholic solution of acetate of
lead. If the oil be pure, there will be but a very slight turbidity,
while the presence of rosin causes a dense flocculent precipitate.
Should linseed oil be adulterated with a non-drying oil, it will remain
sticky for months when spread out in a thin film upon glass or any
other non-absorbent substance.
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