Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
_Manganese Oxalate._--A writer in the _Moniteur de Produits Chimiques_
draws attention to the properties possessed by manganese oxalate as
a drier. This salt has hitherto not had any important industrial
uses, but it can be readily prepared in a state of purity from the
native carbonate by the action of oxalic acid; the author is of the
opinion that it will be found of use for this purpose. If prepared
from carbonate free from iron and lime, it can be obtained as a fine
crystalline white powder, and two-fifths per cent. suffices to bring
about the change. The oxalate is resolved by heat into manganese oxide,
carbonic acid and carbon monoxide, and in the presence of fatty acids
the manganese oxide formed combines with them, the decomposition taking
place at about 130°. The operation is carried out by mixing in a mortar
the oxalate with two or three times its weight of oil, and then adding
the mixture to the main portion of the oil. The heat should be applied
gradually, and the decomposition is known to be complete when there
is no further evolution of gas. The boiled oil, under this treatment,
preserves its limpidity and also remains colourless. Manganese oxalate
has the advantage over oxide of lead, which is commonly employed for
this purpose, in causing the oil to remain transparent when exposed
to sulphur vapours. Manganese acetate has also been used, but it
likewise causes a darkening in the colour of the oil, and the nitrate
is dangerous owing to the possible action of nitric acid on the fats
present in the oil. Manganese borate appears to be next in value to the
oxalate as an oil drier.
In a paper recently read before the Society of Arts, Prof. Hartley
remarked that paint, such as is used for ordinary purposes, is
essentially composed of three materials, without taking into account
the coloured pigments.
(1) White lead, or sublimed zinc-white.
(2) An oil, generally linseed or poppy oil, which is ground up with the
white lead or zinc-white until it becomes a soft paste. This is mixed
with variable preparations of linseed oil and spirit of turpentine.
(3) A substance called dryers, or siccative materials; it may be
linseed oil in which litharge is dissolved, or it may be linseed oil
containing a compound of manganese.
Paint owes to the dryers its property of drying more rapidly than it
would do without it; and it is considered indispensable in buildings
in all cases where paint applied to wood, stone, or metal, would not
be quite dry in 48 hours, or at most in 72 hours, after the first
application.
The first question which requires an answer is, what chemical process
takes place when a paint dries.
Public-domain text, read in full here on John Shaqi.
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