Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
BOILED OIL.--Linseed oil absorbs oxygen; and, when the oil
contains manganese, it absorbs oxygen much more greedily; and when a
manganese oil--that is to say, a boiled oil containing manganese--is
mixed with linseed oil, the substance absorbs oxygen, from a limited
supply of air contained in a closed space, until no trace of any other
gas but nitrogen remains. The power of absorbing oxygen possessed
by 100 volumes of linseed oil, compared with that of 100 volumes of
a mixture of linseed oil and so-called manganese oil, is as 9·4 to
100. This may be termed the measure of its drying power. A mixture
of linseed oil, with a little more than one-fourth of its volume of
manganese oil, has a power of absorbing oxygen four and a half times
greater than either of the components of the mixture taken separately.
In this case Chevreul argues that linseed oil may be considered as a
“dryer” to manganese oil.
Linseed oil, without any addition whatever, if boiled for three hours,
becomes a better drying oil than it was previous to the action of heat.
Oil boiled with 10 per cent, of litharge for three hours, is a much
better dryer than when heated without this oxide.
Oil boiled alone for five hours is an inferior drying oil to one heated
for only three hours.
Oil previously boiled alone for five hours, and boiled alone again for
three hours, is scarcely altered in drying power, but it becomes a
better drying oil if it is boiled the second time with litharge. It is
inferior to a drying oil which has been boiled only three hours with
litharge, without being submitted to a previous boiling.
Oil boiled alone for five hours, boiled for a further period of three
hours with manganese dioxide which has already been used for one
operation, is very nearly as strong a dryer as that which has been
boiled with litharge under the same conditions; but it is superior
to an oil which has been boiled with manganese dioxide for eight
hours. This no doubt arises from the longer boiling with manganese
having caused a larger quantity of manganese to dissolve, and that the
quantity dissolved is in excess of that which yields the best result.
Finally, oil boiled for five hours, and then boiled alone once more
for eight hours, becomes viscous, and the first coat requires a
considerable time to dry. We thus see that the oxides of lead and of
manganese in certain proportions concur with heat in increasing the
drying power of linseed oil. This drying of oils is a process of slow
oxidation.
The following points of Chevreul’s appeared to be difficult of
satisfactory explanation, and suggested to Prof. Hartley an examination
_de novo_ of the facts, as well as an investigation of the chemistry of
the subject generally:--
1. Linseed oil not boiled acted as a dryer to the same oil boiled with
manganese dioxide.
2. Linseed oil, boiled with either litharge or manganese dried more
rapidly when mixed with turpentine.
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