Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
3. Oil, mixed with white lead, zinc white, antimony white, and
arseniate of tin, acts differently, thus:--The white lead dries most
rapidly, the zinc white next, but antimony white and arseniate of tin
are incapable of acting as dryers, in fact, they retard the drying
process.
4. Oil boiled alone for five hours, and boiled for a further period of
three hours with manganese dioxide becomes a superior drying oil to one
which has been boiled with manganese dioxide for eight hours.
From a series of experiments, which were continued for two years, on
twenty-five weighed quantities of raw linseed oil, Prof. Hartley draws
the following deductions:--
1. The chemical action of a manganese compound, when dissolved in
linseed oil, is that of a carrier of oxygen from the atmosphere to the
oil. Manganese oxide takes up oxygen from the air, and transfers it to
the oil, and in so doing it suffers alternately the opposite processes
of oxidation and reduction.
2. To obtain the best result, the amount of manganese present must not
exceed a certain small proportion of the oil.
3. Oil to which turpentine has been added dries more rapidly than oil
without such addition, because the oil being diluted and rendered
thinner, it spreads over a larger surface, and is in contact,
therefore, with a much larger quantity of oxygen.
4. Turpentine does not act as a dryer, that is, as a carrier of oxygen
to linseed oil.
5. Different white pigments behave differently when drying, because
the more powerfully basic the properties of the pigment, the more
powerful is its action as a dryer. Lead oxide and white lead (basic
lead carbonate) combine more easily with the acids of linseed oil than
zinc oxide does. But zinc oxide dries better than antimony oxide,
because it is a stronger base, while arseniate of tin has no basic
properties, therefore does not act as a dryer.
Different substances, that is to say, those without chemical action
on oil, such as lamp-black, sulphate of baryta, and sulphate of lead,
cannot act as “dryers.”
Linseed oil is a glyceride of a peculiar acid, called linoleic acid.
Whatever the exact constitution of linoleic acid may be, linseed oil
for the most part is composed of trilinolein. Raw linseed oil contains
the following constituents:--
1. Glyceride of linoleic acid or trilinolein
{C_{18}H_{31}O}O_{3}.
{ C_{3}H_{5} }
2. Water.
3. Mucilage, with the composition _n_(C_{6}H_{10}O_{5}). On boiling
with dilute acids this yields a gum and a sugar.
4. An essential oil, present in minute proportions, and of unknown
composition.
5. A mixture of colouring matters of intense tinctorial power, viz.
blue and yellow chlorophylls and erythrophyll.
The only useful and desirable substance is the trilinolein.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account