Pigments, Paint and Painting: A practical book for practical men — John Shaqi
Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
(1) By Thénard’s original process, roasted cobalt, from Tunaberg,
Sweden, is dissolved under heat in an excess of nitric acid. The
solution, evaporated nearly to dryness, is boiled in water, and the
deposit of arseniate of iron is filtered out. Into the filtrate is
poured a solution of basic phosphate of soda, which throws down
a precipitate of basic phosphate of cobalt, varying in hue from
violet to pink. This precipitate is washed on a filter, and, while
still gelatinous, 1 lb. of it is intimately mixed with 8 lb. of
hydrated alumina, recently precipitated by ammonia from a solution of
potash-alum. The mass is first dried to brittleness and then calcined
in a covered clay vessel for half an hour at a cherry-red heat. The
resultant blue pigment is stored in glass receptacles.
The preparation of the gelatinous alumina is conducted as follows. The
potash-alum is dissolved in at least three times as much water as is
necessary, and is then precipitated by an abundant excess of ammonia,
with frequent stirring. When settled, the supernatant liquor is
siphoned off, and the precipitate is thoroughly washed several times on
a filter.
Thénard blue will vary in tint according to the proportions of
alumina used. A pure colour is obtained with 4-5 parts alumina to 1
of phosphate of cobalt; a greenish hue with equal parts of alumina
and cobalt salt; and almost any intermediate tone by varying the
proportions between these limits.
(2) To 16 parts of gelatinous alumina add 1 part of arseniate of
cobalt, obtained by precipitating the solution of cobalt by arseniate
of potash.
(3) A richer and more velvety blue is got by using oxide of cobalt and
substituting phosphate of lime for the alumina (Boullai-Marillac).
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