Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
3. Delicate colours are darkened by the oil when exposed to ordinary
town air, that is to say, air which, is not quite pure. This is the
case even when the oils themselves may not injure the paints.
The causes of such alterations is, in nine cases out of ten, the use of
lead dryers.
1. In the first place, boiled oil which contains litharge or other lead
compounds takes a permanent brown colour, which affects the purity of
white lead, zinc white, and delicate pale tints.
2. Lead forms, with extreme ease, lead sulphide, which, in very
minute proportions, is yellow or brown; in larger quantity its colour
is black. The lead sulphide is readily formed by contact with other
sulphides, as, for instance, vermilion, cadmium yellow, and ultramarine.
3. Boiled oil, containing lead, is coloured brown by exposure to air,
owing to the presence of minute quantities of sulphuretted hydrogen,
which causes the formation of lead sulphide.
The remedy is obvious: no oil should be used which has been boiled with
dryers containing lead. In other words, oil should be boiled with pure
manganese compounds only.
In cases where it is desirable to have information of the presence or
absence of lead in a boiled oil, the following test will be found most
useful:--A mixture is made of 4 oz. of glycerine with 1 oz. of ammonium
sulphide, the liquid being kept in a stoppered bottle. Or glycerine is
mixed with an equal volume of water, and saturated with sulphuretted
hydrogen. Half an ounce of the oil to be tested is placed in a white
basin, with the addition of two or three drops of the glycerine
solution. The two liquids are thoroughly incorporated, by stirring with
a strip of glass. A brown or black colour, which gradually appears,
indicates the presence of lead. A pure manganese oil simply becomes
slightly yellow. It is true that, if iron is present, a black colour
might appear, but iron is also an undesirable impurity. Should it be
required to ascertain that the coloration is or is not caused by iron,
two or three drops of glacial acetic acid may be stirred into the oil,
when, if the black colour remains, it is certainly not caused by iron.
Under the old process of oil-boiling at a high temperature, the brown
colour of the oil was, to some extent, an indication that the oil had
been sufficiently heated--that is to say, properly boiled; but in
the modern processes, so largely used, in which oxidation is aided
by a blast of air, this coloration is no indication whatever of the
excellence of the oil; it may be, in fact, the very reverse.
This fact appears to be unknown, or, at any rate, is not a matter
of common knowledge among practical men in this country, who, being
uninformed as to the methods of preparing the oils, consider that a
brown colour is desirable, if not essential.
Public-domain text, read in full here on John Shaqi.
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