Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
When oil-boilers were compelled to adopt some expedient to give a
reddish-brown colour to the oil, they added a small amount of litharge,
the introduction of which actually spoils the oil, and makes it
unsuitable for many purposes to which it is otherwise applicable. Of
late years, pale boiled oils have been more largely manufactured for
special purposes. It is obvious that, for decorative house painting, in
which delicate tints are a leading feature, they may be advantageously
employed.
Notwithstanding that some of the brown oils, when mixed with white
lead, do not entirely retain the brownish tint, but, to some extent,
lose it upon drying, yet they never preserve the whiteness of white
lead. It follows, therefore, that a pale colour in the oil, provided
it is not the yellow colour of raw oil, is greatly to be preferred.
Moreover, when paints are mixed with zinc white, no trace of lead
should be contained in the oil, otherwise, one of the valuable
properties of zinc white pigments is destroyed, namely, its power to
retain its whiteness in the atmosphere of a town, because its colour is
not affected by sulphuretted hydrogen.
Very generally, zinc white and white lead paints are not mixed with
drying oils, but with refined linseed or bleached oil. This, at any
rate, is the practice on the Continent. That is to say, the pigments
are mixed with an oil from which the impurities, and the natural yellow
and red colouring matter, have been removed, so that the colour of the
paint is white. If ordinary oil be used, the paint is more or less
yellow. In order to render such paint quick drying, a certain amount
of dryers, in a solid or liquid form, is added. These dryers almost
invariably contain lead, so that zinc white paint is contaminated by
lead in another way, which may not be suspected, or which is overlooked.
Now as to the chemical action of dryers on oils. Raw oil contains water
and mucilage; the former can be absorbed by anhydrous zinc salts and
by dried alum, and solutions of the salts and the salts themselves are
capable of precipitating mucilage from the oil; hence these substances
cause the impurities to become insoluble, so that they are carried
down as “foots.” Heat greatly facilitates this action, particularly
by causing the oil to become more fluid; and by the action of the
anhydrous salts water is withdrawn from the oil. On the “drying” or
oxidation of the oil, they exert no chemical action whatever.
Zinc linoleate and lead linoleate do not act as dryers when simply
added to the oil. Though the former is soluble in hot oil it is
insoluble in cold oil, and it therefore separates from the oil as it
cools. The latter is very soluble in linseed oil, but only adds to its
drying power when heated therewith.
In conjunction with a high temperature, lead dissolves in oil at the
expense of the glycerine, which is decomposed into acrolein, while lead
linoleate is formed.
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