Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Hartley and Blenkinsop prepare manganese linoleate, and dissolve
this in a hydrocarbon, and add a sufficient quantity of the solution
to the oil, whereby it dissolves easily and mixes completely. By this
treatment, the colouring matter of the oil forms a compound with
the manganese which, while it remains in solution, is very speedily
oxidised in contact with air, especially when a current of air or
oxygen is blown through. The oxidation destroys the colouring matter,
and the manganese compound is deoxidised; subsequently it undergoes
oxidation again, and the products of such oxidation taking place in the
oil are acrolein, formic and acetic acids. After, or concurrently with,
the oxidation of the colouring matters, the oil is oxidised, and, at a
suitable temperature below 132° F., the oil is bleached, increased in
density, and converted into a pale drying oil. By limiting the amount
of the manganese linoleate to that which is capable of just oxidising
the colouring matters, oils may be bleached with very little further
oxidation.
Excellent drying oils have been produced by this process, of a very
pale colour. The oil has been used for decorative house painting, for
both indoor and outdoor work, on wood and on metal. It has also been
used as a coating for iron work, without the addition of a pigment.
The plant used in its production is the same as that employed in
oil-boiling by the usual processes when a blast of air is used.
The advantages of a pale boiled oil, containing no lead, are the
following:--
1. Zinc white retains its pure white colour.
2. Delicate tints, and colours containing sulphides, are not darkened
in course of time.
It may be suggested that for indoor decoration, for the painting of
ships, railway carriages, railway semaphores, signs, and stations,
such oil is free from liability to alter the colours with which it is
mixed, owing to its freedom from lead, which is darkened by traces of
sulphuretted hydrogen in the air to which such paints are exposed.
Gasometers in gas-works may be painted an unalterable white with such
oil and zinc white. But in this case also the zinc white must be free
from lead carbonate or oxide.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account