Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
There are certain objections to each of these methods, which are of
a practical nature: thus, in treating the oil with strong sulphuric
acid, there is too frequently a charring of something, either the oil
itself, or of some impurity therein, and this charring, though it may
be very slight, has the effect of giving a pale brownish tinge to the
oil, which cannot be completely removed by the bleaching process to
which the natural colouring matters in the oil are amenable. It is
quite true that this brown colour separates sometimes, but it is only
after storage for a long period, when a finely divided flocculent
matter separates by subsidence. Treatment with zinc chloride is
satisfactory but expensive. Perfectly pure manganese sulphate, which
is a neutral salt, has been used by Hartley and Blenkinsop in very
strong solution, and where there is an objection to using an acid.
For ordinary purposes, perfectly satisfactory results are obtained
by the use of a dilute sulphuric acid containing about 30 per cent.
of H_{2}SO_{4}, since, though it possesses the power of withdrawing
water from the oil, it may remain in contact therewith without causing
any charring, and at the same time it causes the precipitation in a
complete and rapid manner of all the mucilage. A purified linseed
oil is thus produced which is bright, clear, and slightly yellowish
in colour, though somewhat paler than the ordinary oil. It is
important that the strength of the oil should not exceed that degree
of concentration which is sufficient for the purpose for which it is
intended. The oil having been so treated, and the impurities separated
by subsidence or otherwise, it is next submitted to the bleaching and
oxidising treatment.
Binks bleached oils with oxides of manganese dissolved in the oil, but
difficulty was experienced in carefully regulating the quantity of
the manganese compounds which were to be introduced into the oil. For
instance, he precipitated manganous hydroxide in contact with oil, and
added the mixture to the bulk of the material, and he also modified the
treatment by dissolving manganous hydroxide in ammonia, and added the
solution to the oil.
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