Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The large proportions of potash and phosphates contained in the
insoluble residues render them well suited for use in the manufacture
of artificial manures. As already mentioned, when regarded from a
scientific or economical point of view, the yellow prussiate industry
is carried on under very imperfect conditions. In addition to the
amount of potash, there is a very considerable waste of nitrogen,
firstly, because the larger proportion of that element present in the
animal substances is not converted into cyanogen at all, but passes
off chiefly in the form of ammonia salts; and, secondly, because
part of the potassium cyanide which is actually produced is lost by
decomposition, and another portion is left in the mother liquor. It
has been calculated that out of every 100 parts of ferrocyanide which
should theoretically be obtained, 4 parts are lost when fairly pure
materials have been employed, and 14 in the case of impure ingredients.
The following analyses indicate the percentage composition of two
samples of insoluble residue:--
No. 1. No. 2.
Sulphate of potash, &c. 9·06 3·21
Phosphates of lime, magnesia and iron 13·74 6·24
Oxide of iron 13·34 19·58
Lime and magnesia 5·08 7·23
Sand and silica 23·97 29·24
Charcoal and moisture 34·81 34·50
------ ------
100·00 100·00
According to Karmrodt, the following proportions of the nitrogen
contained in various animal substances are actually converted into
cyanogen during the manufacture of yellow prussiate of potash:--
Per cent.
Woollen rags 16
Horn 20
Leather cuttings 33
Cow hair 14
Dried blood 16
Horn charcoal 56
Rag charcoal 33
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