Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
“Again, according to Ritter, ultramarine contains a double silicate,
not only associated with polysulphide, but also with thiosulphate of
soda; and Schülzenberger, on the other hand, considers that it is a
mixture of a double silicate with sulphite and monosulphide of sodium.
“Endemann considers that the blue colour is due to a ‘colour nucleus,’
consisting of unchanging proportions of aluminium, sodium, oxygen and
sulphur, in each variety of ultramarine the proportion being different,
while the rest of the sodium and aluminium and the whole of the silica
merely act as a vehicle necessary to the preparation and existence
of the colour. He considers that this ‘colour nucleus,’ in the case
of white ultramarine, which he calls the ‘mother-substance in the
manufacture of blue ultramarine,’ has the formula AlNa_{4}O_{2}S_{2}.
By the action on two molecules of this of sulphurous acid gas,
Na_{2}O is removed, and green ultramarine Al_{2}Na_{6}O_{3}S_{4}
is formed, which then, by the action of oxygen, which forms sodium
sulphate, passes into the pure green compound, having the formula
Al_{2}Na_{4}O_{3}S_{3}. In the ‘indirect process’ of manufacture, green
ultramarine is converted into blue by being burned with sulphur. By
this means Endemann considers that more sodium and sulphur are removed,
and blue ultramarine Al_{2}Na_{2}O_{3}S_{3} is formed. He considers
that the other portion, not included in the ‘colour nucleus,’ differs
in different samples. In one which he mentions it has about the
composition 3Al_{2}O_{3}.5Na_{2}O.16SiO_{2}.
Public-domain text, read in full here on John Shaqi.
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