Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
(2) A modification of (1), followed by Guignet, was to replace the
bichromate of potash by chromate of soda, prepared by dissolving in
boiling water 61 parts of neutral chromate of potash and 53 parts of
nitrate of soda. For the neutral chromate of potash, also, may be
substituted a mixture of 92 parts of bichromate of potash and 89 parts
of crystallised carbonate of soda, the nitrate of soda remaining as
before. On cooling, in either case, the solution deposits much nitrate
of potash, which is commercially valuable. The chromate of soda present
in the mother liquors is obtained by evaporating to dryness. The
pigment produced by the chromate of soda process is lighter in colour
than that obtained with bichromate of potash. It may be still further
paled by adding a little alumina, baryta, or other white pigment to the
bichromate and boracic acid mixture before calcining.
(3) Equal quantities of potash bichromate and potato starch are
thoroughly mixed and then calcined in a crucible at a high temperature.
The product is washed with boiling water, to remove the potash
carbonate formed, and any remaining undecomposed bichromate. The
precipitated chromium oxide is filtered, dried, and again calcined to
drive off the water. The final result is a handsome pigment which flows
well from the brush.
(4) On heating in a crucible a mixture of 3 parts of neutral chromate
of potash with 2 parts of salammoniac, the two salts are decomposed,
the result being formation of chromium oxide mixed with potassium
chloride, which latter is removed by several washings with hot water.
The brilliancy of the chromium oxide is enhanced by calcination at a
dull red heat.
(5) Fuse together 3 parts of boracic acid and 1 part of potash
bichromate at a dull red heat on the hearth of a reverberatory furnace.
Thus is formed a borate of chromium and potash, with evolution of
oxygen. The mass is repeatedly washed with boiling water, which causes
decomposition, and consequent separation of hydrated oxide of chromium,
and a soluble borate of potash. The chromium oxide is washed, and
ground very fine.
(6) When a solution of potash bichromate is poured into a neutral
solution of mercury proto-nitrate, it forms an orange-coloured
precipitate, which is washed and gently dried, then powdered, and
heated in a stoneware retort provided with an arm dipping into cold
water, by which the mercury is distilled and condensed. The residue in
the retort is a highly comminuted chromium oxide, of a fine dark-green
colour.
(7) On calcining potash bichromate in a crucible at a very high
temperature, it is decomposed, and results in chromium oxide and
potash, the latter of which can be washed out. The chromium oxide thus
obtained is very dense and of a dark-green colour resembling (6).
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