Pleasant Ways in ScienceProctor, Richard A. (Richard Anthony)
Science
Pleasant Ways in Science
Proctor, Richard A. (Richard Anthony)
Science
In passing, I must note a circumstance in which some of those who have
dealt with this special part of the spectroscopic evidence have erred.
It is true in one sense that some elements may be of such a nature that
their vapours cannot rise so high in the solar atmosphere as those of
other elements. But it must not be supposed that the denser vapours
seek a lower level, the lighter vapours rising higher. According to
the known laws of gaseous diffusion, a gas or vapour diffuses itself
throughout a space occupied by another gas or several other gases,
in the same way as though the space were not occupied at all. If we
introduce into a vessel full of common air a quantity of carbonic
acid gas (I follow the older and more familiar nomenclature), this
gas, although of much higher specific gravity than either oxygen or
nitrogen, does not take its place at the bottom of the vessel, but so
diffuses itself that the air of the upper part of the vessel contains
exactly the same quantity of carbonic acid gas as the air of the
lower part. Similarly, if hydrogen is introduced, it does not seek
the upper part of the vessel, but diffuses itself uniformly throughout
the vessel. If we enclose the carbonic acid gas in a light silken
covering, and the hydrogen in another (at the same pressure as the air
in the vessel) one little balloon will sink and the other will rise;
but this is simply because diffusion is prevented. It may be asked
how this agrees with what I have said above, that some elements may
not exist in sufficient quantity or in suitable condition above the
sun’s photospheric level to give any spectroscope evidence of their
nature. As to quantity, indeed, the answer is obvious: if there is only
a small quantity of any given element in the entire mass of the sun,
only a very small quantity can under any circumstances exist outside
the photosphere. As regards condition, it must be remembered that the
vessel of my illustrative case was supposed to contain air at a given
temperature and pressure throughout. If the vessel was so large that
in different parts of it the temperature and pressure were different,
the diffusion would, indeed, still be perfect, because at all ordinary
temperatures and pressures hydrogen and carbonic acid gas remain
gaseous. But if the vapour introduced is of such a nature that at
moderate temperatures and pressures it condenses, wholly or in part, or
liquefies, the diffusion will not take place with the same uniformity.
We need not go further for illustration than to the case of our own
atmosphere as it actually exists. The vapour of water spreads uniformly
through each layer of the atmosphere which is at such a temperature
and pressure as to permit of such diffusion; but where the temperature
is too low for complete diffusion (at the actual pressure) the aqueous
vapour is condensed into visible cloud, diffusion being checked at
this point as at an impassable boundary. In the case of the sun, as
Public-domain text, read in full here on John Shaqi.
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