Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
The cottage in which the family lived that had suffered so severely was
situated about 20 or 30 yards from the shaft of a disused coal mine, and
was the end house of a row of cottages. It had a cellar opening into the
outer air, but this opening was usually covered over by means of a piece
of wood. The adjoining house to this, the occupants of which had for
some time suffered from headache, although to a less extent, had a
cellar with a similar opening, but supplied with an ill-fitting cover.
The house on the opposite side of the road, in which the two birds were
found dead, had a cellar opening both at the front and the back; but
both these openings, until a little before the occurrence detailed, had
been kept closed. The cellars in all cases communicated with the houses
by means of doors opening into the kitchens. According to the general
account of the occupants, the cellars had smelled of “fire stink,”
which, in their opinion, proceeded from the adjoining mine.
The shaft of the disused mine communicated with a mine in working order,
and, to encourage the ventilation in this mine, a furnace had for some
weeks been lit and suspended in the shaft. This furnace had set fire to
the coal in the disused mine and smoke had been issuing from the shaft
for four weeks previously. Two days previous to the inquiry the opening
of the shaft had been closed over with a view to extinguish the fire.
Dr. Reid considered, from the symptoms and all the circumstances of the
case, that the illness was due to carbon monoxide gas penetrating into
the cellars from the mine, and from thence to the living- and
sleeping-rooms. A sample of the air yielded 0·015 per cent. of carbon
monoxide, although the sample had been taken after the cellar windows
had been open for twenty-four hours.
§ 42. =Detection of Carbon Monoxide.=--It may often be necessary to
detect carbon monoxide in air and to estimate its amount. The detection
in air, if the carbon monoxide is in any quantity, is easy enough; but
traces of carbon monoxide are difficult. Where amounts of carbon
monoxide in air from half a per cent. upwards are reasonably presumed to
exist, the air is measured in a gas measuring apparatus and passed into
an absorption pipette charged with alkaline pyrogallic acid, and when
all the oxygen has been abstracted, then the residual nitrogen and gases
are submitted to an ammoniacal solution of cuprous chloride.
Public-domain text, read in full here on John Shaqi.
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