Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
The solution of cuprous chloride is prepared by dissolving 10·3 grms. of
copper oxide in 150 c.c. of strong hydrochloric acid and filling the
flask with copper turnings; the copper reduces the cupric chloride to
cuprous chloride; the end of the reduction is known by the solution
becoming colourless. The colourless acid solution is poured into some
1500 c.c. of water, and the cuprous chloride settles to the bottom as a
precipitate. The supernatant fluid is poured off as completely as
possible and the precipitate washed into a quarter litre flask, with 100
to 150 c.c. of distilled water and ammonia led into the solution until
it becomes of a pale blue colour. The solution is made up to 200 c.c. so
as to contain about 7·3 grms. per cent. of cuprous chloride.
Such a solution is an absorbent of carbon monoxide; it also absorbs
ethylene and acetylene.
A solution of cuprous chloride which has absorbed CO gives it up on
being treated with potassic bichromate and acid. It has been proposed by
Wanklyn to deprive large quantities of air of oxygen, then to absorb any
carbon monoxide present with cuprous chloride, and, lastly, to free the
cuprous chloride from the last gas by treatment with acid bichromate, so
as to be able to study the properties of a small quantity of pure gas.
By far the most reliable method to detect small quantities of carbon
monoxide is, however, as proposed by Hempel, to absorb it in the lungs
of a living animal.
A mouse is placed between two funnels joined together at their mouths by
a band of thin rubber; one of the ends of the double funnel is connected
with an aspirator, and the air thus sucked through, say for half an hour
or more; the mouse is then killed by drowning, and a control mouse,
which has not been exposed to a CO atmosphere, is also drowned; the
bodies of both mice are cut in two in the region of the heart, and the
blood collected. Each sample of blood is diluted in the same proportion
and spectroscopically examined in the manner detailed at p. 58.
Winkler found that, when large volumes of gas were used (at least 10
litres), 0·05 per cent. of carbon monoxide could be readily detected.
II.--Chlorine.
§ 43. Chlorine is a yellow-green gas, which may, by cold and pressure,
be condensed into a liquid. Its specific gravity is, as compared with
hydrogen, 35·37; as compared with air, 2·45; a litre under standard
conditions weighs 3·167 grms. It is soluble in water.
The usual method of preparation is the addition of hydrochloric acid to
bleaching powder, which latter substance is hypochlorite of lime mixed
with calcic chloride and, it may be, a little caustic lime. Another
method is to treat manganese dioxide with hydrochloric acid or to act on
manganese dioxide and common salt with sulphuric acid.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account