Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
There should be no difficulty in recognising acetic acid; the odour
alone is, in most cases, strong and unmistakable. Traces are
detected by distilling, neutralising the distillate by soda,
evaporating to dryness, and treating the residue as follows:--A
portion warmed with alcohol and sulphuric acid gives a smell of
acetic ether. Another portion is heated in a small tube of hard
glass with arsenious acid; if acetic acid is present, or an acetate,
a smell of kakodyl is produced.
V.--Ammonia.
§ 91. Ammonia, (NH₃), is met with either as a vapour or gas, or as a
solution of the pure gas in water.
=Properties.=--Pure ammonia gas is colourless, with a strong,
irritating, pungent odour, forming white fumes of ammonic chloride, if
exposed to hydric chloride vapour, and turning red moist litmus-paper
strongly blue. By intense cold, or by a pressure of 6½ atmospheres at
the ordinary temperature, the gas is readily liquefied; the liquid
ammonia boils at 38°; its observed specific gravity is ·731; it freezes
at -57·1°. Ammonia is readily absorbed by water; at 0° water will take
up 1000 times its own volume, and at ordinary temperatures about 600
times its volume. Alcohol also absorbs about 10 per cent. Ammonia is a
strong base, and forms a number of salts. Ammonia is one of the constant
products of the putrefaction of nitrogenous substances; it exists in the
atmosphere in small proportions, and in everything that contains water.
Indeed, water is the only compound equal to it in its universality of
diffusion. The minute quantities of ammonia thus diffused throughout
nature are probably never in the free state, but combinations of ammonia
with hydric nitrate, carbon dioxide, &c.
§ 92. =Uses.=[115]--A solution of ammonia in water has many applications
in the arts and industries; it is used in medicine, and is an
indispensable laboratory reagent.
[115] Sir B. W. Richardson has shown that ammonia possesses powerful
antiseptic properties.--_Brit. Med. Journal_, 1862.
The officinal caustic preparations of ammonia are--_ammoniæ liquor
fortior_ (_strong solution of ammonia_), which should contain 32·5 per
cent. of ammonia, and have a specific gravity of ·891.
_Liquor ammoniæ_ (_solution of ammonia_), specific gravity ·959, and
containing 10 per cent. of ammonia. There is also a _liniment of
ammonia_, composed of olive oil, 3 parts, and ammonia, 1 part.
_Spiritus Ammoniæ Fœtidus_ (_fœtid spirit of ammonia_).--A solution of
assafœtida in rectified spirit and ammonia solution, 100 parts by
measure, contains 10 of strong solution of ammonia.
Strong solution of ammonia is an important ingredient in the
“_linimentum camphoræ composita_” (_compound liniment of camphor_), the
composition of which is as follows:--camphor, 2·5 parts; oil of
lavender, ·125; strong solution of ammonia, 5·0; and rectified spirit,
15 parts. Its content of strong solution of ammonia is then about 22·6
per cent. (equivalent to 7·3 of NH₃).[116]
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