Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
[116] There is a common liniment for horses used in stables, and
popularly known as “white oil.” It contains 1 part of ammonia, and 4
parts of olive or rape oil; not unfrequently turpentine is added.
Another veterinary liniment, called “egg oil,” contains ammonia, oil of
origanum, turpentine, and the yelks of eggs.
_The carbonate of ammonia_ is also caustic; it is considered to be a
compound of acid carbonate of ammonium, NH₄HCO₃, with carbamate of
ammonium, NH₄NH₂CO₂. It is in the form of colourless, crystalline
masses; the odour is powerfully ammoniacal; it is strongly alkaline, and
the taste is acrid. It completely volatilises with heat, is soluble in
water, and somewhat soluble in spirit.
The officinal preparation is the “_spiritus ammoniæ aromaticus_,” or
aromatic spirit of ammonia. It is made by distilling in a particular way
ammonic carbonate, 4 ozs.; strong solution of ammonia, 8 ozs.; rectified
spirit, 120 ozs.; water, 60 ozs.; volatile oil of nutmeg, 4½ drms.; and
oil of lemon, 6½ drms. Aromatic spirit of ammonia is a solution in a
weak spirit of neutral carbonate, flavoured with oil of lemon and
nutmeg; the specific gravity should be 0·896.
_Smelling salts_ (_sal volatile_) are composed of carbonate of ammonia.
§ 93. =Statistics.=--Falck has found throughout literature notices of
thirty cases of poisoning by ammonia, or some of its preparations. In
two of these it was used as a poison for the purpose of murder, and in
eight with suicidal intent; the remainder were all accidental. The two
criminal cases were those of children, who both died. Six out of eight
of the suicidal, and twelve of the twenty accidental cases also
terminated fatally.
Ammonia was the cause of 64 deaths (39 male, 25 female) by accident and
of 34 (18 male, 16 female) by suicide, making a total of 98 during the
ten years 1883-1892 in England and Wales. At present it occupies the
seventh place among poisons as a cause of accident, the ninth as a means
of suicide.
§ 94. =Poisoning by Ammonia Vapour.=--Strong ammoniacal vapour is fatal
to both animal and vegetable life. There are, however, but few instances
of poisoning by ammonia vapour; these few cases have been, without
exception, the result of accident. Two cases of death are recorded, due
to an attempt to rouse epileptics from stupor, by an injudicious use of
strong ammonia applied to the nostrils. In another case, when
hydrocyanic acid had been taken, there was the same result. An instance
is also on record of poisonous effects from the breaking of a bottle of
ammonia, and the sudden evolution in this way of an enormous volume of
the caustic gas. Lastly, a man employed in the manufacture of ice, by
means of the liquefaction of ammonia (Carré’s process), breathed the
vapour, and had a narrow escape for his life.
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