Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
It is polymerised by the action of strong sulphuric acid, the
polymer, of course, boiling at a higher temperature than the
original oil. With water it forms a crystalline hydrate
(C₁₀H₂₀O₂,H₂O). On passing nitrosyl chloride gas into the oil,
either pure or diluted with chloroform or alcohol, the mixture being
cooled by ice, a white crystalline body is deposited, of the formula
C₁₀H₁₆(NOCl). By treating this compound with alcoholic potash, the
substitution product (C₁₀H₁₆NO) is obtained. By treating turpentine
with an equal bulk of warm water, and shaking it in a large bottle
with air, camphoric acid and peroxide of hydrogen are formed. When
turpentine oil is left in contact with concentrated hydrochloric
acid, there is formed terebenthene dihydrochloride (C₁₀H₁₆2HCl),
which forms rhombic plates, insoluble in water, and decomposable by
boiling alcoholic potash, with formation of terpinol, (C₁₀H₁₇)₂O.
The dihydrochloride gives a colour-reaction with ferric chloride.
This is an excellent test--not, it is true, confined to oil of
turpentine--but common to the dihydrochlorides of all the terpenes.
A few drops of the oil are stirred in a porcelain capsule with a
drop of hydrochloric acid, and one of ferric chloride solution; on
gently heating, there is produced first a rose colour, then a
violet-red, and lastly a blue.
§ 152. =Effects of the Administration of Turpentine.=--L. W.
Liersch[143] exposed animals to the vapour of turpentine, and found
that a cat and a rabbit died within half an hour. There was observed
uneasiness, reeling, want of power in the limbs (more especially in
the hinder extremities), convulsions partial, or general, difficulty
of respiration; and the heart’s action was quickened. Death took
place, in part, from asphyxia, and in part was attributable to a
direct action on the nervous centres. The autopsy showed congestion
of the lungs, ecchymoses of the kidney, and much blood in the liver
and spleen. Small doses of turpentine-vapour cause (according to Sir
B. W. Richardson)[144] giddiness, deficient appetite, and anæmia.
From half an ounce to an ounce is frequently prescribed in the
country as a remedy for tape-worm; in smaller quantities it is found
to be a useful medicine in a great variety of ailments. The larger
doses produce a kind of intoxication with giddiness, followed often
by purging and strangury, not unfrequently blood and albumen (or
both) is found in the urine. When in medical practice I have given
the oil, and seen it given by others, in large doses for tape-worm
to adults, in perhaps 40 cases, but in no one instance were the
symptoms severe; the slight intoxication subsided quickly, and in a
few hours the patients recovered completely. Nevertheless it has
been known to destroy the lives of children, and cause most serious
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