Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
symptoms in adults. Two fatal cases are mentioned by Taylor; one was
that of a child who died fifteen hours after taking half an ounce of
the oil; in another an infant, five months old, died rapidly from a
teaspoonful. The symptoms in these fatal cases were profound coma
and slight convulsions; the pupils were contracted, and there was
slow and irregular breathing. Turpentine is eliminated in a changed
form by the kidneys, and imparts an odour of violet to the urine;
but the nature of the odoriferous principle has not yet been
investigated.
[143] Clarus in Schmidt’s _Jahrbücher_, Bd. cxvii., i. 1863; and
_Vierteljahrsschr. für ger. Med._, xxii., Oct. 1862.
[144] _Brit. and For. Med.-Chir. Review_, April 1863.
II.--Camphor.
§ 153. A great many essential oils deposit, after exposure to air,
camphors produced by oxidation of their terpenes. Ordinary camphor
is imported in the rough state from China and Japan, and is prepared
by distilling with water the wood of _Camphora officinarum_; it is
resublimed in England. The formula of camphor is C₁₀H₁₆O; it has a
density of ·986 to ·996; melts at 175°, and boils at 205°. It is
readily sublimed, especially in a vacuum, and is indeed so volatile
at all temperatures, that a lump of camphor exposed to the air
wastes away. It is somewhat insoluble in water (about 1 part in
1000), but this is enough to impart a distinct taste to the water;
it is insoluble in chloroform, ether, acetone, acetic acid, carbon
disulphide, and oils. It has a fragrant odour and a burning taste. A
10 per cent. solution in alcohol turns a ray of polarised light to
the right +42·8°. By distillation with zinc chloride, cymene and
other products are produced. By prolonged treatment with nitric
acid, camphor is oxidised to camphoric acid (C₁₀H₁₆O₄). Camphor
unites with bromine to form a crystalline, unstable dibromide, which
splits up on distillation into hydrobromic acid and monobrom-camphor
(C₁₀H₁₅BrO). The latter is used in medicine; it crystallises in
prisms fusible at 76°, and is readily soluble in alcohol.
§ 154. =Pharmaceutical Preparations.=--The preparations officinal in
the British Pharmacopœia are _camphor water_--water saturated with
camphor, containing about one part per thousand.
=Camphor Liniment.=--A solution of camphor in olive oil, strength 25
per cent.
=Compound Camphor Liniment.=--Composed of camphor, oil of lavender,
strong solution of ammonia and alcohol; strength in camphor about 11
per cent.
=Spirit of Camphor.=--A solution of camphor in spirit; strength, 10
per cent.
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