Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
§ 215. =Potassic xanthogenate= (CS₂C₂H₅OK) and =potassic
xanthamylate= (CS₂C₅H₁₁OK) (the latter being prepared by the
substitution of amyl alcohol for ethyl alcohol), both on the
application of a heat below that of the body, develop CS₂, and are
poisonous, inducing symptoms very similar to those already detailed.
IX.--The Tar Acids--Phenol--Cresol.
§ 216. =Carbolic Acid. Syn. Phenol, Phenyl Alcohol, Phenylic Hydrate;
Phenic Acid; Coal-Tar Creasote.=--The formula for carbolic acid is
C₆H₅HO. The pure substance appears at the ordinary temperature as a
colourless solid, crystallising in long prisms; the fusibility of the
crystals is given variously by different authors: from my own
observation, the pure crystals melt at 40°-41°, any lower melting-point
being due to the presence of cresylic acid or other impurity; the
crystals again become solid about 15°. Melted carbolic acid forms a
colourless limpid fluid, sinking in water. It boils under the ordinary
pressure at 182°, and distils without decomposition; it is very readily
and completely distilled in a vacuum at about the temperature of 100°.
After the crystals have been exposed to the air, they absorb water, and
a hydrate is formed containing 16·07 per cent. of water. The hydrate
melts at 17°, any greater hydration prevents the crystallisation of the
acid; a carbolic acid, containing about 27 per cent. of water, and
probably corresponding to the formula C₆H₆O,2H₂O, is obtained by
gradually adding water to carbolic acid so long as it continues to be
dissolved. Such a hydrate dissolves in 11·1 times its measure of water,
and contains 8·56 per cent. of real carbolic acid. Carbolic acid does
not redden litmus, but produces a greasy stain on paper, disappearing on
exposure to the air; it has a peculiar smell, a burning numbing taste,
and in the fluid state it strongly refracts light. Heated to a high
temperature it takes fire, and burns with a sooty flame.
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