Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
That bromine-water precipitates several volatile and fixed alkaloids
from their solutions is no objection to the bromine test, for it may be
applied to a distillation product, the bases having been previously
fixed by sulphuric acid. Besides, the properties of tri-bromo-phenol are
distinct enough, and therefore there is no valid objection to the test.
It is the best hitherto discovered. There are also other reactions, such
as that Millon’s reagent strikes a red--molybdic acid, in concentrated
sulphuric acid, a blue--and potassic dichromate, with sulphuric acid, a
brown colour--but to these there are objections. Again, we have the
_Euchlorine_ test, in which the procedure is as follows:--A test-tube is
taken, and concentrated hydrochloric acid is allowed to act therein upon
potassic chlorate. After the gas has been evolved for from 30 to 40
seconds, the liquid is diluted with 1½ volume of water, the gas removed
by blowing through a tube, and solution of strong ammonia poured in so
as to form a layer on the top; after blowing out the white fumes of
ammonium chloride, a few drops of the sample to be tested are added. In
the presence of carbolic acid, a rose-red, blood-red, or red-brown tint
is produced, according to the quantity present. Carbolic acid may be
confounded with _cresol_ or with _creasote_, but the distinction between
pure carbolic acid, pure cresol, and creasote is plain.
§ 232. =Cresol (Cresylic Acid, Methyl-phenol)=,
OH
/
C₆H₄ .
\
CH₃
--There are three cresols--ortho-, meta-, and para-. Ordinary
commercial cresol is a mixture of the three, but contains but little
ortho-cresol; the more important properties of the pure cresols are set
out in the following table:--
+--------+-----------------+----------------+---------------------+
| | Melting-point. | Boiling-point. | Converted by fusion |
| | | | with Potash into-- |
+--------+-----------------+----------------+---------------------+
|Ortho-, | 31-31·5° C. | 188·0° | Salicylic Acid |
| | | | (Ortho-oxybenzoic |
| | | | acid). |
| | | | |
|Meta-, |Fluid at ordinary| 201·0° | Meta-oxybenzoic |
| | temperature. | | acid. |
| | | | |
|Para-, | 36° | 198° |Para-oxybenzoic acid.|
+--------+-----------------+----------------+---------------------+
Pure ortho-, meta-, or para-cresol have been obtained by synthetical
methods; they cannot be said to be in ordinary commerce.
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