Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
British Pharmacopœia, Switzerland, and Bor. (vj), 2
France, 10
Vauquelin’s Acid, 3·3
Scheele’s „ 4 to 5[234]
Riner’s „ 10
Robiquet’s „ 50
Schraeder’s „ 1·5
Duflos’ „ 9
Pfaff’s „ 10
Koller’s „ 25
[234] Strength very uncertain.
In English commerce, the analyst will scarcely meet with any acid
stronger than Scheele’s 5 per cent.
Impure oil of bitter almonds contains hydric cyanide in variable
quantity, from 5 per cent. up to 14 per cent. There is an officinal
preparation obtained by digesting cherry-laurel leaves in water, and
then distilling a certain portion over. This _Aqua Lauro-cerasi_ belongs
to the old school of pharmacy, and is of uncertain strength, but varies
from ·7 to 1 per cent. of HCN.
§ 253. =Poisoning by Prussic Acid.=--Irrespective of suicidal or
criminal poisoning, accidents from prussic acid may occur--
1. From the use of the cyanides in the arts.
2. From the somewhat extensive distribution of the acid, or rather of
prussic-acid producing substances in the vegetable kingdom.
1. =In the Arts.=--The galvanic silvering[235] and gilding of metals,
photography, the colouring of black silks, the manufacture of Berlin
blue, the dyeing of woollen cloth, and in a few other manufacturing
processes, the alkaline cyanides are used, and not unfrequently fumes of
prussic acid developed.
[235] The preparation used for the silvering of copper vessels is a
solution of cyanide of silver in potassic cyanide, to which is added
finely powdered chalk. Manipulations with this fluid easily develop
hydrocyanic acid fumes, which, in one case related by Martin (_Aerztl.
Intelligenzbl._, p. 135, 1872), were powerful enough to produce symptoms
of poisoning.
2. =In the Animal Kingdom.=--One of the myriapods (_Chilognathen_)
contains glands at the roots of the hairs, which secrete prussic acid;
when the insect is seized, the poisonous secretion is poured out from
the so-called _foramina repugnatoria_.
3. =In the Vegetable Kingdom.=--A few plants contain cyanides, and many
contain amygdalin, or bodies formed on the type of amygdalin. In the
presence of emulsin (or similar principles) and water, this breaks up
into prussic acid and other compounds--an interesting reaction usually
represented thus--
C₂₀H₂₇NO₁₁ + 2H₂O = CNH + C₇H₆O + 2C₆H₁₂O₆.
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