Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
1 equivalent of amygdalin--_i.e._, 457 parts--yielding 1 equivalent of
CNH or 27 parts; in other words, 100 parts of amygdalin yield
theoretically 5·909 parts of prussic acid,[236] so that, the amount of
either being known, the other can be calculated from it.
[236] According to Liebig and Wöhler, 17 grms. of amygdalin yield 1 of
prussic acid (_i.e._, 5·7 per cent.) and 8 of oil of bitter almonds.
Thirty-four parts of amygdalin, mixed with 66 of emulsin of almonds,
give a fluid equalling the strength of acid of most pharmacopœias, viz.,
2 per cent.
Greshoff[237] has discovered an amygdalin-like glucoside in the two
tropical trees _Pygeum parriflorum_ and _P. latifolium_. The same author
states that the leaves of _Gymnema latifolium_, one of the Asclepiads,
yields to distillation benzaldehyde hydrocyanide. Both _Lasia_ and
_Cyrtosperma_, plants belonging to the natural family of the Orontads,
contain in their flowers potassic cyanide. _Pangium edule_, according to
Greshoff, contains so much potassic cyanide that he was able to prepare
a considerable quantity of that salt from one sample of the plant. An
Indian plant (_Hydnocarpus inebrians_) also contains a cyanide, and has
been used for the purpose of destroying fish. Among the Tiliads,
Greshoff found that _Echinocarpus Sigun_ yielded hydrocyanic acid on
distillation. Even the common linseed contains a glucoside which breaks
up into sugar, prussic acid, and a ketone.
[237] M. Greshoff--_Erster Bericht über die Untersuchung von
Pflanzenstoffen Niederländisch-Indiens. Mittheilungen aus dem
chemisch-pharmakologischen Laboratorium des botan. Gartens des Staates_,
vii., Batavia, 1890, Niederländisch. Dr. Greshoff’s research indicates
that there are several other cyanide-yielding plants than those
mentioned in the text.
The following plants, with many others, all yield, by appropriate
treatment, more or less prussic acid:--Bitter almonds (_Amygdalus
communis_); the _Amygdalus persica_; the cherry laurel (_Prunus
laurocerasus_); the kernels of the plum (_Prunus domestica_); the bark,
leaves, flowers, and fruit of the wild service-tree (_Prunus padus_);
the kernels of the common cherry and the apple; the leaves of the
_Prunus capricida_; the bark of the _Pr. virginiana_; the flowers and
kernels of the _Pr. spinosa_; the leaves of the _Cerasus acida_; the
bark and almost all parts of the _Sorbus aucuparia_, _S. hybrida_, and
_S. torminalis_; the young twigs of the _Cratægus oxyacantha_; the
leaves and partly also the flowers of the shrubby _Spiræaceæ_, such as
_Spiræa aruncus_, _S. sorbifolia_, and _S. japonica_;[238] together with
the roots of the bitter and sweet _Cassava_.
[238] The bark and green parts of the _Prunus avium_, L., _Prunus
mahaleb_, L., and herbaceous _Spirææ_ yield no prussic acid.
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