Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
In only a few of these, however, has the exact amount of either prussic
acid or amygdalin been determined; 1 grm. of bitter almond pulp is about
equal to 2½ mgrms. of anhydrous prussic acid. The kernels from the
stones of the cherry, according to Geiseler, yield 3 per cent. of
amygdalin; therefore, 1 grm. equals 1·7 mgrm. of HCN.
§ 254. The wild service-tree (_Prunus padus_) and the cherry-laurel
(_Prunus Laurocerasus_) contain, not amygdalin but a compound of
amygdalin with amygdalic acid; to this has been given the name of
laurocerasin. It was formerly known as amorphous amygdalin; its formula
is C₄₀H₅₅NO₂₄; 933 parts are equivalent to 27 of hydric cyanide--that
is, 100 parts equal to 2·89.
In the bark of the service-tree, Lehmann found ·7 per cent. of
laurocerasin (= ·02 HCN), and in the leaves of the cherry-laurel 1·38
per cent. (= 0·39 HCN).
Francis,[239] in a research on the prussic acid in cassava root, gives
as the mean in the sweet cassava ·0168 per cent., in the bitter ·0275
per cent., the maximum in each being respectively ·0238 per cent., and
·0442 per cent. The bitter-fresh cassava root has long been known as a
very dangerous poison; but the sweet has hitherto been considered
harmless, although it is evident that it also contains a considerable
quantity of prussic acid.
[239] “On Prussic Acid from Cassava,” _Analyst_, April 1877, p. 5.
The kernels of the peach contain about 2·85 per cent. amygdalin (= ·17
HCN); those of the plum ·96 per cent. (= ·056 HCN); and apple pips ·6
per cent. (= ·035 per cent. HCN).
It is of great practical value to know, even approximately, the quantity
of prussic acid contained in various fruits, since it has been adopted
as a defence in criminal cases that the deceased was poisoned by prussic
acid developed in substances eaten.
§ 255. =Statistics.=--Poisoning by the cyanides (prussic acid or
cyanide of potassium) occupies the third place among poisons in order
of frequency in this country, and accounts for about 40 deaths annually.
In the ten years ending 1892 there were recorded no less than 395 cases
of accidental, suicidal, or homicidal poisoning by prussic acid and
potassic cyanide. The further statistical details may be gathered from
the following tables:--
DEATHS IN ENGLAND AND WALES DURING THE TEN YEARS 1883-1892 FROM PRUSSIC
ACID AND POTASSIC CYANIDE.
PRUSSIC ACID (ACCIDENT OR NEGLIGENCE).
Ages, 0-1 1-5 5-15 15-25 25-65 65 and Total
above
Males, ... 1 1 1 12 1 16
Females, 1 1 ... 2 7 ... 11
--------------------------------------------
Totals, 1 2 1 3 19 1 27
--------------------------------------------
CYANIDE OF POTASSIUM (ACCIDENT OR NEGLIGENCE).
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