The generally accepted notion of a caloric, or heat-stuff, was strongly
shaken by the work of Mayer and Joule. If the quantity of heat can be
increased and diminished, people said, heat cannot be a substance, but
must be a _motion_. The subordinate part of this statement has become
much more popular than all the rest of the doctrine of energy. But we
may convince ourselves that the motional conception of heat is now as
unessential as was formerly its conception as a substance. Both ideas
were favored or impeded solely by accidental historical circumstances.
It does not follow that heat is not a substance from the fact that a
mechanical equivalent exists for quantity of heat. We will make this
clear by the following question which bright students have sometimes put
to me. Is there a mechanical equivalent of electricity as there is a
mechanical equivalent of heat? Yes, and no. There is no mechanical
equivalent of _quantity_ of electricity as there is an equivalent of
_quantity_ of heat, because the same quantity of electricity has a very
different capacity for work, according to the circumstances in which it
is placed; but there _is_ a mechanical equivalent of electrical energy.
Let us ask another question. Is there a mechanical equivalent of water?
No, there is no mechanical equivalent of quantity of water, but there is
a mechanical equivalent of weight of water multiplied by its distance
of descent.
When a Leyden jar is discharged and work thereby performed, we do not
picture to ourselves that the quantity of electricity disappears as work
is done, but we simply assume that the electricities come into different
positions, equal quantities of positive and negative electricity being
united with one another.
What, now, is the reason of this difference of view in our treatment of
heat and of electricity? The reason is purely historical, wholly
conventional, and, what is still more important, is wholly indifferent.
I may be allowed to establish this assertion.
In 1785 Coulomb constructed his torsion balance, by which he was enabled
to measure the repulsion of electrified bodies. Suppose we have two
small balls, _A_, _B_, which over their whole extent are similarly
electrified. These two balls will exert on one another, at a certain
distance _r_ of their centres, a certain repulsion _p_. We bring into
contact with _B_ now a ball _C_, suffer both to be equally electrified,
and then measure the repulsion of _B_ from _A_ and of _C_ from _A_ at
the same distance _r_. The sum of these repulsions is again _p_.
Accordingly something has remained constant. If we ascribe this effect
to a substance, then we infer naturally its constancy. But the essential
point of the exposition is the divisibility of the electric force _p_
and not the simile of substance.
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