In 1838 Riess constructed his electrical air-thermometer (the
thermoelectrometer). This gives a measure of the quantity of heat
produced by the discharge of jars. This quantity of heat is not
proportional to the quantity of electricity contained in the jar by
Coulomb's measure, but if _Q_ be this quantity and _C_ be the capacity,
is proportional to _Q_²/2_C_, or, more simply still, to the energy of
the charged jar. If, now, we discharge the jar completely through the
thermometer, we obtain a certain quantity of heat, _W_. But if we make
the discharge through the thermometer into a second jar, we obtain a
quantity less than _W_. But we may obtain the remainder by completely
discharging both jars through the air-thermometer, when it will again be
proportional to the energy of the two jars. On the first, incomplete
discharge, accordingly, a part of the electricity's capacity for work
was lost.
When the charge of a jar produces heat its energy is changed and its
value by Riess's thermometer is decreased. But by Coulomb's measure the
quantity remains unaltered.
Now let us imagine that Riess's thermometer had been invented before
Coulomb's torsion balance, which is not a difficult feat, since both
inventions are independent of each other; what would be more natural
than that the "quantity" of electricity contained in a jar should be
measured by the heat produced in the thermometer? But then, this
so-called quantity of electricity would decrease on the production of
heat or on the performance of work, whereas it now remains unchanged;
in that case, therefore, electricity would not be a _substance_ but a
_motion_, whereas now it is still a substance. The reason, therefore,
why we have other notions of electricity than we have of heat, is purely
historical, accidental, and conventional.
This is also the case with other physical things. Water does not
disappear when work is done. Why? Because we measure quantity of water
with scales, just as we do electricity. But suppose the capacity of
water for work were called quantity, and had to be measured, therefore,
by a mill instead of by scales; then this quantity also would disappear
as it performed the work. It may, now, be easily conceived that many
substances are not so easily got at as water. In that case we should be
unable to carry out the one kind of measurement with the scales whilst
many other modes of measurement would still be left us.
In the case of heat, now, the historically established measure of
"quantity" is accidentally the work-value of the heat. Accordingly, its
quantity disappears when work is done. But that heat is not a substance
follows from this as little as does the opposite conclusion that it is a
substance. In Black's case the quantity of heat remains constant because
the heat passes into no _other_ form of energy.
Public-domain text, read in full here on John Shaqi.
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