Let us consider what takes place during the firing of a paste of this
latter description. After all the water, including that in combination
in the kaolin, has been driven off, we have, as the temperature rises,
an intimate mixture of two silicates, one of which, if heated alone,
would be unaltered by any temperature at our command--this is the
silicate of alumina derived from the kaolin; while the other is a
fusible silicate of alumina and potash. There is also present a certain
amount of free silica. There is reason to believe that at a certain
point a chemical reaction takes place between these constituents,
accompanied by a local rapid rise of temperature in the materials, the
rise being due to this reaction. As a result there is a rearrangement of
the molecules of the mass, although no complete fusion takes place. It
is now, says M. Vernadsky (_Comptes Rendus_, 1890, p. 1377)--we are now
following the account of his experiments--that the sub-crystalline
rods--the baculites of which we have already spoken--are formed. M.
Vernadsky claims to have separated these rods from the glassy base by
means of hydrofluoric acid, in which the former were insoluble. He found
them to consist of a very basic silicate of alumina, containing as much
as 70 per cent. of that earth, while the glassy base was chiefly
composed of silica in combination with the potash and with a small
quantity of alumina. In their optical properties the crystals or
baculites resemble the mineral known as sillimanite, a natural silicate
of alumina.
This is all that scientific research has so far been able to tell us of
the intimate constitution of porcelain; but as far as it goes, it is
evidence in favour of our claim that we are dealing with a definite
substance, _sui generis_, and not merely with a casual mixture of
certain superior kinds of clay, something, as we have said, between
glass and stoneware.
There are certain other elements that enter at times into the
composition of porcelain--magnesia, which may have been added to the
paste in the form either of steatite or magnesite; and lime, derived
either from gypsum or chalk. These additions generally tend to increase
the fusibility of the paste, especially when accompanied by an
additional dose of silica; but as their presence is not essential we are
not concerned with these substances here.
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