=123. Summary of Data.=—If a solution of a soluble sulfate, chloride or
nitrate of an alkali or an alkaline-earth metal be placed in contact
with a soil, the result is that the soil takes up a part of the base but
none of the acid. This absorption of base is attended with the
liberation of some other base from the soil which combines with the acid
of the solution. Any alkali or alkaline earth base has the power of
replacing any other such base. However, if soluble phosphates and
silicates of these bases be placed in contact with the soil both the
base and the acid are removed from the solution.
Peters[82] has shown that the amount of absorption depends upon the
concentration of the solution, the relation between the quantity of
solution and the soil and the kind of salt used. He treated 100 grams of
earth with 250 cubic centimeters of solutions of different potash salts
with the following results:
Strength of solution. ⅒ Normal. ¹⁄₂₀ Normal.
Grams Grams
Salt Used K₂O absorbed. K₂O absorbed.
KCl 0.3124 0.1990
K₂SO₄ 0.3362 0.2098
K₂CO₃ 0.5747 0.3154
Biedermann[83] proves that, for phosphoric acid at least, the absorption
increases with the temperature.
It has also been found that the amount of absorption depends upon the
time of contact between the soil and solution. Way found that the
absorption of ammonia was complete in half an hour, while Henneberg and
Stohmann[84] noticed that the phosphoric acid continued to be fixed
after the expiration of twenty-four hours.
It is a very important fact that the absorption of a base is never
complete; no matter how dilute the solution it will still carry a small
portion of the base with it. Peters states that it requires about 28,000
parts of water to remove one part of absorbed potash and Stohmann found
that it required about 10,000 parts of water to remove one part of
absorbed ammonia. With phosphoric acid, the resulting compound seems to
be much more insoluble.
According to Tuxen[85] the presence of salts of soda and potash in
solution decreases the power of a soil to absorb ammonia compounds and
the presence of sodium salts decreases the power of a soil to absorb
potash. On the other hand the presence of potassium compounds
considerably increases the absorption of phosphoric acid. He further
affirms that the compounds of potash, phosphoric acid, etc., formed in
the soil, are decidedly more soluble in sodium salts than in pure water.
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