by the soil the two bulbs shown on the small glass tubes connecting with
A can be filled with red litmus paper. This paper will at once be turned
blue in the lower bulb while in the upper one it will retain its
original color because the liquid in passing through the soil will have
lost its alkaline reaction. The solutions used should be very dilute.
The apparatus is designed for lecture experiments and not for
quantitative determinations.
=135. Method of Knop.=—For rapid determination of the absorption
coefficient of the soil Knop’s method may be used.[98]
The fine earth which is employed is that which passes a sieve with
meshes of half a millimeter. From 50 to 100 grams of this soil are mixed
with from five to ten grams of powdered chalk and with about twice the
weight of ammonium chlorid solution of known strength, _viz._, from 100
to 200 cubic centimeters. The ammonia solution should be of such a
concentration that the ammonia by its decomposition for each cubic
centimeter of the liquid evolves exactly one cubic centimeter of
nitrogen. This solution is prepared by dissolving in 208 cubic
centimeters of water one gram of ammonium chlorid. With frequent shaking
the solution is allowed to stand in contact with the soil for
forty-eight hours. The whole is now allowed to settle and the
supernatant clear liquid is poured through a dry filter. From the
filtrate twenty to forty cubic centimeters are removed by a pipette, and
evaporated to dryness in a small porcelain dish, with the addition of a
drop of pure hydrochloric acid. The ammonium chlorid remaining in the
porcelain dish is washed with ten cubic centimeters of water into one of
the compartments of the evolution flask of the Knop-Wagner azotometer.
It is decomposed with fifty cubic centimeters of bromin lye and the
nitrogen estimated volumetrically. The difference between the amount of
nitrogen in this material and that of the original material will give
the amount of absorption exercised by the fine earth. This number,
without any further calculation, can be taken as the coefficient of
absorption.
=136. Method of Huston.=—The salt solutions recommended by Huston[99]
are sodium phosphate (Na₂HPO₄), potassium chlorid, potassium sulfate,
ammonium sulfate and sodium nitrate.
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