In regard to the mechanical actions which take place between the
particles, Hilgard considers them as irregular spheroids, each of which
can at best come in contact at three points with any other particle. The
cause of aggregation cannot therefore be mere surface adhesion
independent of the liquid, and the particles being submerged there is no
meniscus to create an adhesive tension.
Since experiment shows that the flocculative tendency is measurably
increased by the cohesion coefficient of the liquid, it seems necessary
to assume that capillary films of the latter interposed between the
surfaces of solids create a considerable adhesive tension even in the
absence of a meniscus.
=182. Effect of Potential of Surface Particles.=—Whitney suggests that
this is due to the potential of the surface particles of solids and
liquids.[123] The potential of a single water particle is the work which
would be required to pull it away from the surrounding water particles
and remove it beyond their sphere of attraction. For simplicity, it may
be described as the total force of attraction between a single particle
and all other particles which surround it. With this definition, it will
be seen that the potential of a particle on an exposed surface of water
is only one-half of the potential in the interior of the mass, as half
of the particles which formerly surrounded and attracted it were removed
when the other exposed surface of water was separated from it. A
particle on an exposed surface of water, being under a low potential,
will therefore tend to move toward the center of the mass where the
potential, _i. e._, the total attraction, is greater, and the surface
will tend to contract so as to leave the fewest possible number of
particles on the surface. This is surface tension.
If, instead of air, there is a solid substance in contact with the
water, the potential will be greater than on an exposed surface of the
liquid, for the much greater number of solid particles will have a
greater attraction for the water particles than the air particles had.
They may have so great an attraction that the water particle on this
surface, separating the solid and liquid, may be under greater potential
than prevails in the interior of the liquid mass. Then the surface will
tend to expand as much as possible, for the particles in the interior of
the mass of liquid will try to get out on the surface. This is the
reverse of surface tension. It is surface pressure, which may exist on a
surface separating a solid and liquid.
Muddy water may remain turbid for an indefinite time, but if a trace of
lime or salt be added to the water the grains of clay flocculate, that
is, they come together in loose, light flocks, like curdled milk, and
settle quickly to the bottom, leaving the liquid above them clear.
Ammonia and some other substances tend to prevent this and to keep the
grains apart if flocculation has already taken place.
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