If two small grains of clay, suspended in water, come close together
they may be attracted to each other or not, according to the potential
of the water particles on the surface of the clay. If the potential of
the surface particle of water is less than that of the particle in the
interior of the mass of liquid, there will be surface tension, and the
two grains will come together and be held with some force, as their
close contact will diminish the number of surface particles in the
liquid. If, on the other hand, the potential of the particle on the
surface of the liquid is greater than of the particle in the interior of
the mass, the water surface around the grains will tend to enlarge, as
there will be greater attraction for the water particles there than in
the interior of the mass of liquid, and the grains of clay will not come
close together and will even be held apart, as their close contact would
diminish the number of surface particles in the liquid around them.
=183. Influence of Surface Tension.=—Hilgard supposes that the surface
tension which is assumed to exist between two liquid surfaces must exert
a corresponding influence between the surfaces of solids and liquids,
apart from any meniscal action.
It is then to be expected that the adhesion of the particles
constituting one of these floccules will be very materially increased
whenever the formation of menisci between them becomes possible by the
removal of the general liquid mass. Suppose one of the floccules to be
stranded, it will, in the first place, remain immersed in a sensibly
spherical drop of liquid. As this liquid evaporates, the spherical
surface will become pitted with menisci forming between the single
projecting particles, and as these menisci diminish their radius by
still further evaporation, the force with which they hold the particles
together will increase until it reaches a maximum. As the evaporation
progresses beyond this point of maximum, the adhesion of the constituent
particles must diminish by reason of the disappearance of the smaller
menisci, and when finally the point is reached when liquid water ceases
to exist between the surfaces, the slightest touch, or sometimes even
the weight of the particles themselves, will cause a complete
dissolution of the floccule, which then flattens down into a pile of
single granules.
In regard to natural deposits from water, Hilgard supposes that they are
always precipitated in a flocculated state. The particles of less than
two-tenths millimeter diameter are carried down with those of a larger
diameter having much higher hydraulic value. Thus the deposition of a
pure clay can take place under only very exceptionable circumstances.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account