In a number of tall glass jars fine clay is stirred with water, and the
results of precipitation watched. In all cases it will be noticed that
the clay rapidly separates into two portions, the greater part quickly
settling down to the bottom of the jars, and the smaller part remaining
suspended for a greater or less length of time.
The power which water possesses of sustaining clay is gradually
destroyed by the addition of an acid or salt; a very small quantity, for
instance, of sulfuric acid, is sufficient to precipitate the clay with
great rapidity. In solutions of sulfuric acid and sodium chlorid of
varying strengths, suspended clay is precipitated in the order of the
specific gravity of the solutions, the densest solutions being the last
to clear up. This may be due to the greater viscosity of the denser
liquids.
The power which water possesses of sustaining clay is gradually
decreased by the addition of small quantities of certain salts and of
lime.
=187. Effect of Chemical Action=—Brewer[125] emphasizes the importance
of chemical action in the flocculation of clays. As expressed by him the
chemical aspects of the phenomena of sedimentation have either been
lightly considered or entirely ignored. Brewer is led to believe that
the action of clay thus suspended is analogous to that of a colloidal
body. Like a colloid, when diffused in water, the bulk of the mass is
very great, shrinking enormously on drying. He therefore concludes that
clays probably exist in suspension as a series of hydrous silicates
feebly holding different proportions of water in combination and having
different properties so far as their behavior to water is concerned.
Some of them he supposes swell up in water much as boiled starch does,
and are diffusible in it with different degrees of facility, and that
the strata observed on long standing of jars of suspended clay represent
different members of this series of chemical compounds which hold their
different proportions of combined water very feebly and are stable under
a very limited range of conditions.
These compounds are probably destroyed or changed in the presence of
acids, salts and various other substances, and are stable only under
certain conditions of temperature, those which exist at one temperature
being destroyed or changed to other compounds at a different
temperature.
=188. Theory of Barus.=—Brewer’s hypothesis, however, is not in harmony
with the demonstration of Barus, who proves that a given particle of
clay has the same density in ether as in water.
The physical and mathematical aspects of sedimentation have also been
carefully studied by Barus.[126] The mathematical conditions of a fine
particle suspended in a liquid and free from the influences of
flocculation are described by Barus in the following equations.
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