If P be the resistance encountered by a solid spherule of radius r,
moving through a viscous liquid at the rate x, and if k be the
frictional coefficient, then P = 6πkrx. Again, the effective part of the
weight of the particle is P´ = ⁴⁄₃πr³ (ρ-ρ´)g, where g is the
acceleration of gravity and ρ and ρ´ the density of solid particle and
liquid, respectively. In case of uniform motion P = P´. Hence x = 2/9kr²
(ρ-ρ´)g ... (1).
In any given case of thoroughly triturated material the particles vary
in size from a very small to a relatively large value; but by far the
greater number approach a certain mean figure and dimension. An example
of this condition of things may be formulated. To avoid mathematical
entanglement let y = Ax^{³⁄₂}e^{-x²} ... (2) where y is the probable
occurrence of the rate of subsidence x. If now the turbidity of the
liquid (avoiding optical considerations) be defined as proportional to
the mass of solid material particles suspended in unit of volume of
liquid, then the degree of turbidity which the given ydx particles add
to the liquid is, _caeteris paribus_, proportional to r³ydx, where r is
the mean radius. Hence the turbidity, T, at the outset of the experiment
(immediately after shaking), is T = T₀∫₀^∞r³ydx = T₀, where equations
(1) and (2) have been incorporated.
If the plane at a depth d below the surface of the liquid be regarded,
then at a time after shaking the residual turbidity is
(3) ... T_{d} = T₀∫^{d/t}₀r³ydx = T₀(1 − (1 + (d²/t² × e^{-d²/t²}))
The equation describes the observed occurrences fairly well.
The phenomena of stratification observed by Brewer are explained by
Barus from the above formula: In proportion as the time of subsidence is
greater, the tube shows opacity at the bottom, shading off gradually
upward, through translucency, into clearness at the top. If, instead of
equation (2), there be introduced the condition of a more abrupt
maximum, if, in other words, the particles be very nearly of the same
size, then subsidence must take place in unbroken column capped by a
plane surface which at the time zero coincided with the free surface of
the liquid. Again, suppose one-half of the particles of this column
differ in some way uniformly from the other half. Then at the outset
there are two continuous columns coinciding, or, as it were,
interpenetrating throughout their extent. But the rate of subsidence of
these two columns is necessarily different, since the particles, each
for each, differ in density, radius and frictional qualities, by given
fixed amounts. Hence the two surfaces of demarcation at the time zero
coincided with the free surface. In general, if there be n groups of
particles uniformly distributed, then at the time zero n continuous
columns interpenetrate and coincide throughout their extent. At the time
t, the free surface will be represented by n consecutive surfaces of
demarcation below it, each of which caps a column, the particles of
which form a distinct group.
Public-domain text, read in full here on John Shaqi.
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