From a further discussion of the mathematical condition under which the
subsidence of the particles takes place, Barus is of the opinion that
Durham’s theory of suspension being only a lower limit of solution is
rapidly gaining ground, yet without being attended with concise
experimental evidence which will account for the differences in the rate
of subsidence. On the contrary, Brewer’s hypothesis of colloidal
hydrates is more easily subjected to experimental proof. The test shows
that the particles retain their normal density, no matter how they are
suspended or circumstanced.
Further, in the explanation of the phenomenon of sedimentation, the
following principle may be regarded as determined; namely, if particles
of a comminuted solid are shaken up in a liquid, the distribution of
parts after shaking will tend to take place in such a way that the
potential energy of the system of solid particles and liquid, at every
stage of subsidence, is the minimum compatible with the given
conditions.
According to Barus it is necessary, in order to pass judgment on the
validity of any of the given hypotheses, to have in hand better
statistics of the size of the particles relatively to the water
molecule, than are now available. Inasmuch as the particles in pure
water are individualized and granular, it is apparently at once
permissible to infer the size of the particles from the observed rates
of subsidence. His observations show that the said rate decreases in
marked degree with the turbidity of the mixture. Hence the known formulæ
for single particles are not rigorously applicable, though it cannot be
asserted whether the cause of discrepancy is physical or mathematical in
kind. It follows that special deductions must be made for the subsidence
of stated groups of particles before an estimate of their mean size can
fairly be obtained.
Rowland[127] reaches a closer approximation for the fall of a single
particle by showing that the liquid, even at a large distance from the
particle, is not at rest.
In the case of water, however, it is noticed that despite the large
surface energy of the liquid, subsidence takes place in such a way that
for a given mass of suspended sediment the surfaces of separation are a
maximum. On the other hand, in case of subsidence in ether or in salt
solutions, the solid particles behave much like the capillary spherules
of a heavy liquid shaken up in a lighter liquid with which it does not
mix. In other words, the tendency here is to reduce surfaces of
separation to the least possible value, large particles growing in mass
and bulk mechanically at the expense of smaller particles; in other
words, exhibiting the phenomenon of flocculation.
Public-domain text, read in full here on John Shaqi.
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