As a result of numerous analyses it is concluded, first, that the oxygen
exists normally in the atmosphere of soils in large proportion; second,
very probably the gaseous atmosphere of arable soils, to a depth of
sixty centimeters, contains scarcely one per cent of carbon dioxid and
about twenty per cent of oxygen; third, the highest percentages of
carbon dioxid correspond to epochs of highest temperature and periods of
greatest calm; fourth, the proportion of carbon dioxid increases
ordinarily with the depth at which the samples are taken. This
disposition of the carbon dioxid would appear almost necessary, since
near the surface the internal atmosphere is almost constantly diluted by
external air by virtue of diffusion. Fifth, from one epoch to another
the composition of the atmosphere of the soil can undergo considerable
variation.
=287. Determination of Diffusion of Carbon Dioxid in Soil.=—The method
proposed by Hannén[188] is a convenient one to use in studying the rate
of diffusion of carbon dioxid in soils. A large Woulff’s bottle with
three necks serves for the reception of the gas. The two smaller outer
necks of the bottle carry two glass tubes bent outwards and provided
with stop-cocks. One of these passes to near the bottom of the bottle
and the other just through the stopper. The middle tubule of the bottle
is of a size to give in section an area of about twenty-two square
centimeters. It is made with a heavy rim two centimeters wide and plane
ground. This rim carries a plane-ground glass plate with a circular
perforation in one-half of it, of the size of the opening in the central
tubule of the bottle. A glass cylinder, carrying a fine wire-gauze
diaphragm near the lower end, fits with a ground-glass edge air-tight,
over this aperture, being held in position by a brass clamp. The
ground-glass plate moves air-tight between the cylinder and the bottle,
so that the cylinder can be brought into connection with the bottle or
cut off therefrom without in any way opening the bottle to the air. The
plate and all ground movable surfaces should be well lubricated with
vaseline.
The experiment is carried on as follows: The glass cylinder is filled
with the soil to be tested, closed above with a rubber stopper carrying
a gas tube, and then by moving the perforated-glass plate brought into
connection with the bottle. The side tube, with short arm inside the
bottle, is then closed, and carbon dioxid introduced through the other
lateral tube until the gas passing from the tube at the top of the
cylinder is pure carbon dioxid.
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