It may be well to add here the probable reason as given by Whitney for
this, _viz._, that the deeper color shows that the oxids of iron and the
organic compounds have less oxygen and indicate that the soils are quite
retentive of moisture and rather tend to the exclusion of air, so that
part of the oxygen of the iron compounds and of the organic matters has
been used up in the oxidation processes within the soil. It is known,
for example, that wood oxidizes much more rapidly around a rusty nail
than where it is simply exposed to the air, the iron oxid acting as a
carrier between the oxygen of the air and the organic matter. In a sandy
soil, on the contrary, where there is usually less moisture and much
freer circulation of air, the iron compounds have more oxygen and
usually have a light yellow color. If this sand is heated, however, with
the exclusion of air, and especially in the presence of organic matters,
part of this oxygen will be given off and there will be the same red
color as in the heavier clay soils. It is frequently noticed, also, in
compact clays that where air gains access through cracks or root-holes,
the color is altogether modified.
=94. Determination of Color.=—There is no process which will give
experimentally and accurately the color of a soil sample. The changes
which the color of a soil undergoes in passing from a saturated to an
anhydrous state are well-marked. The analyst will have to be content
with giving as nearly as possible a description of the color of the
sample when taken and the changes which it undergoes in air drying or on
heating in a bath to 100°–110°, or in heating to redness with or without
exclusion of the air. These changes in color will give some indication
of the character of the organic and mineral matters present.
=95. Odoriferous Matters in Soil.=—It is known that the soil emits a
peculiar odor which is not disagreeable except when it has been recently
wet, for instance, after a short rain. Several attempts have been made
to discover the nature of this odor. These researches have established
the fact that the essential principle of this odor resides in an organic
compound of a neutral nature of the aromatic family and which is carried
by the vapor of water after the manner of a body possessing a feeble
tension. The odor is penetrating, almost piquant, and analogous to that
of camphorated and quite distinct from other known substances. In regard
to the quantity of this substance, it is extremely minute and can be
regarded as being only a few millionths of a per cent.
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