_Titrated Uranium Solution._—Two hundred and fifty grams of uranium
nitrate are dissolved in water, twenty-five grams of sodium acetate
added, and the whole diluted to seven liters. One cubic centimeter of
this solution corresponds to about 0.005 gram of phosphorus pentoxid.
In order to determine its exact value proceed as follows: Twenty-five
cubic centimeters of the calcium phosphate solution which, for example,
has been found to contain 0.10317 gram of phosphorus pentoxid, are
neutralized in a porcelain dish with ammonia, acidified with acetic,
treated with ten cubic centimeters of sodium acetate solution, and
warmed. Through a burette as much uranium solution is allowed to flow
as is necessary to show in a drop of the solution taken out of the
dish, when treated with a drop of pure potassium ferrocyanid, a slight
brown color. In order to be certain, this operation is repeated two or
three times with new quantities of twenty-five cubic centimeters of
calcium phosphate solution. Example:
Twenty-five cubic centimeters of the calcium phosphate solution
containing 0.10317 gram of phosphorus pentoxid, gave as a mean of three
determinations 23.2 cubic centimeters of the uranium solution necessary
to produce the brown color with potassium ferrocyanid. Consequently
0.10317 ÷ 23.2 = 0.00445 gram of phosphorus pentoxid equivalent
to one cubic centimeter of uranium solution. If, for instance, a
quantity of fertilizer weighing exactly five grams, require ten cubic
centimeters of the uranium solution for the complete precipitation of
its phosphoric acid, then the quantity of phosphoric acid contained in
the fertilizer would be equivalent to 10 × 0.0045, equivalent to 0.0445
gram of phosphorus pentoxid. The fertilizer, therefore, contains eight
and nine-tenths per cent of phosphorus pentoxid.
_Conduct of the Molybdenum Method._—This method rests upon the
precipitation of the phosphorus pentoxid by a solution of ammonium
molybdate in nitric acid, solution of the precipitate in ammonia, and
subsequent precipitation with magnesia.
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