A résumé of the important methods, in a form suited to use in a factory
for preparing phosphatic fertilizers for the market, seems desirable.
In these factories the chemists have been accustomed to use their
own, or private methods, and there has not been a general disposition
among them to publish their methods and experience for the common
benefit. For factory processes, a method should be not only reasonably
accurate, but also simple and rapid. It is evident, therefore, that
the general principles already indicated must underlie any method
which would prove useful to factory work. Albert has made a résumé of
such methods applicable for factory control, and these are given here
for convenience, although they are, in many respects, but condensed
statements of methods already described.[98]
=116. Reagents.=—_Molybdate Solution._—One hundred and ten grams of
pure molybdic acid are dissolved in ammonia of nine-tenths specific
gravity and diluted with water to one liter. The solution is poured
into one liter of nitric acid, of one and two-tenths specific gravity,
and, after standing a few days, filtered.
_Concentrated Ammonium Nitrate Solution._—Seven hundred and fifty grams
of pure ammonium nitrate are dissolved in water and made up to one
liter.
_Magnesia Mixture._—Fifty-five grams of magnesium chlorid; seventy
grams of ammonium chlorid; 130 cubic centimeters of ammonia of
nine-tenths specific gravity are dissolved and diluted with water to
one liter.
_Two and One-Half Per Cent Ammonia._—One hundred cubic centimeters of
ammonia of nine-tenths specific gravity are diluted with water to one
liter.
_Joulie’s Citrate Solution._—Four hundred grams of citric acid are
dissolved in ammonia of nine-tenths specific gravity and diluted to one
liter with ammonia of the same strength.
_Wagner’s Citrate Solution._—One hundred and fifty grams of citric acid
are exactly neutralized with ammonia, then ten grams of citric acid
added and diluted to one liter with water.
_Sodium Acetate Solution._—One hundred grams of sodium acetate,
crystallized, are dissolved in water, treated with 100 cubic
centimeters of acetic acid, and diluted to one liter with water.
_Calcium Phosphate Solution._—About ten grams of dry, pure tribasic
calcium phosphate are dissolved in nitric acid and diluted with water
to one liter. In this solution the phosphoric acid is determined
gravimetrically by the molybdate or citrate method, and the value of
the solution marked on the flask containing it.
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