_Example_: Let the corrected reading of the barometer at the
time of noting the volume of the gas be 740 millimeters, and the
volume of the gas reduced to 0° be 32.18 cubic centimeters. What
will this volume be at a pressure of 760 millimeters?
Substituting the proper values in the formula, we have:
(32.18 × 740)
V′ = ------------- = 31.33
760
Therefore, a volume of nitrogen which occupies a space of thirty-five
cubic centimeters at a temperature of 22°, and at a barometric pressure
of 740 millimeters, becomes 31.33 cubic centimeters at a temperature of
0° and a pressure of 760 millimeters.
One liter of nitrogen at 0° and 760 millimeters pressure weighs 1.25456
grams; and one cubic centimeter therefore 0.00125456 gram. To find the
weight of gas obtained in the above supposed analysis, it will only be
necessary to multiply this number by the volume of nitrogen expressed
in cubic centimeters under the standard conditions; _viz._, 0.0125456 ×
31.33 = 0.039305 gram. If the sample taken for analysis weighed half a
gram, the percentage of nitrogen found would be 7.85.
=164. Tension of the Aqueous Vapor.=—It has been shown by experience
that when a gas is collected over a potash solution containing fifty
per cent of potassium hydroxid, the tension of the aqueous vapor is
so far diminished as to be of no perceptible influence on the final
result. To correct the volume of a gas, therefore, so collected for
this tension, would involve an unnecessary calculation for practical
purposes. If a gas thus collected should be transferred to a burette
over mercury, on which some water floats, then the correction should be
made.
At 0° the tension of aqueous vapor will support a column of mercury
4.525 millimeters high, and at 40° one of 54.969 millimeters.
The following table gives the tension of aqueous vapors in millimeters
of a mercurial column for each degree of temperature from zero to forty.
Tension of Tension of
vapor in vapor in
Temperature. millimeters. Temperature. millimeters.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account