6Ca(PO₃)₂ + 2CaH₂P₂O₇ = 8Ca(PO₃)₂ + 2H₂O.
Provided the drying is made at once at 210° the sum of the changes
produced as indicated above, can be represented by the following
formula:
8[CaH₄(PO₄)₂·H₂O] = 8Ca(PO₃)₂ + 24H₂O.
COMPLETE ANALYSIS OF MINERAL PHOSPHATES.
=19. Constituents to be Determined.=—The most important point in
the analysis of mineral phosphates is to determine their content of
phosphoric acid. Of equal scientific interest, however, and often of
great commercial importance is the determination of the percentage of
other acids and bases present. The analyst is often called on, in the
examination of these bodies, to make known the content of water both
free and combined, of organic and volatile matter, of carbon dioxid,
sulfur, chlorin, fluorin, silica, iron, alumina, calcium, manganese,
magnesia, and the alkalies. The estimation of some of these bodies
presents problems of considerable difficulty, and it would be vain to
suppose that the best possible methods are now known. Especially is
this the case with the processes which relate to the estimation of the
fluorin, silica, iron, alumina, and lime. The phosphoric acid, however,
which is the chief constituent from a commercial point of view, it
is believed, can now be determined with a high degree of precision.
Often the estimation of some of the less important constituents is of
great interest in determining the origin of the deposits, especially
in the case of fluorin. While the merchant is content with knowing the
percentage of phosphoric acid and the manufacturer asks in addition
only some knowledge of the quantity of iron, alumina, and lime the
analyst in most cases is only content with a complete knowledge of the
constitution of the sample at his disposal.
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